How softness matters in soft nanogels and nanogel assemblies

A Scotti, MF Schulte, CG Lopez, JJ Crassous… - Chemical …, 2022 - ACS Publications
Softness plays a key role in determining the macroscopic properties of colloidal systems,
from synthetic nanogels to biological macromolecules, from viruses to star polymers …

Nanogels and microgels: From model colloids to applications, recent developments, and future trends

M Karg, A Pich, T Hellweg, T Hoare, LA Lyon… - Langmuir, 2019 - ACS Publications
Nanogels and microgels are soft, deformable, and penetrable objects with an internal gel-
like structure that is swollen by the dispersing solvent. Their softness and the potential to …

Design, characterization and applications of nanocolloidal hydrogels

SM Morozova, A Gevorkian… - Chemical Society Reviews, 2023 - pubs.rsc.org
Nanocolloidal gels (NCGs) are an emerging class of soft matter, in which nanoparticles act
as building blocks of the colloidal network. Chemical or physical crosslinking enables NCG …

The entropy-controlled strategy in self-assembling systems

X Zhang, X Dai, L Gao, D Xu, H Wan, Y Wang… - Chemical Society …, 2023 - pubs.rsc.org
Self-assembly of various building blocks has been considered as a powerful approach to
generate novel materials with tailorable structures and optimal properties. Understanding …

Pathways and challenges towards a complete characterization of microgels

F Scheffold - Nature communications, 2020 - nature.com
Due to their controlled size, sensitivity to external stimuli, and ease-of-use, microgel colloids
are unique building blocks for soft materials made by crosslinking polymers on the …

Microgels adsorbed at liquid–liquid interfaces: A joint numerical and experimental study

F Camerin, MA Fernández-Rodríguez, L Rovigatti… - ACS …, 2019 - ACS Publications
Soft particles display highly versatile properties with respect to hard colloids and even more
so at fluid–fluid interfaces. In particular, microgels, consisting of a cross-linked polymer …

The Asakura–Oosawa theory: Entropic forces in physics, biology, and soft matter

K Miyazaki, KS Schweizer, D Thirumalai… - The Journal of …, 2022 - pubs.aip.org
Note: This paper is part of the JCP Special Topic on Depletion Forces and Asakura–Oosawa
Theory. a) Electronic mail: miyazaki@ r. phys. nagoya-u. ac. jp b) Electronic mail …

Relationship between rheology and structure of interpenetrating, deforming and compressing microgels

GM Conley, C Zhang, P Aebischer, JL Harden… - Nature …, 2019 - nature.com
Thermosensitive microgels are widely studied hybrid systems combining properties of
polymers and colloidal particles in a unique way. Due to their complex morphology, their …

Resolving the different bulk moduli within individual soft nanogels using small-angle neutron scattering

JE Houston, L Fruhner, A de la Cotte… - Science …, 2022 - science.org
The bulk modulus, K, quantifies the elastic response of an object to an isotropic
compression. For soft compressible colloids, knowing K is essential to accurately predict the …

The microscopic role of deformation in the dynamics of soft colloids

N Gnan, E Zaccarelli - Nature Physics, 2019 - nature.com
Soft colloids enable the exploration of states with densities exceeding that of random close
packing, but it remains unclear whether softness controls the dynamics under these dense …