Ynamides: a modern functional group for the new millennium

KA DeKorver, H Li, AG Lohse, R Hayashi, Z Lu… - Chemical …, 2010‏ - ACS Publications
Alkynes represent one of the most important and versatile building blocks in organic
synthesis. Heteroatom-substituted alkynes, which can be considered as subgroups of …

Ynamides: versatile tools in organic synthesis

G Evano, A Coste, K Jouvin - … Chemie International Edition, 2010‏ - Wiley Online Library
Ynamides display an exceptionally fine balance between stability and reactivity. They also
offer unique and multiple opportunities for the inclusion of nitrogen‐based functionalities into …

Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

DS Surry, SL Buchwald - Chemical Science, 2011‏ - pubs.rsc.org
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions
and have been applied in a range of contexts. This perspective attempts to aid the reader in …

MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts

P García-García, M Müller, A Corma - Chemical Science, 2014‏ - pubs.rsc.org
Metal–organic frameworks have recently attracted attention as heterogeneous catalysts due
to their high content of metal centres and large surface area and pore volume, along with …

Cu-catalyzed oxidative amidation of propiolic acids under air via decarboxylative coupling

W Jia, N Jiao - Organic Letters, 2010‏ - ACS Publications
Cu-Catalyzed Oxidative Amidation of Propiolic Acids Under Air via Decarboxylative Coupling |
Organic Letters Recently Viewedclose modal ACS ACS Publications C&EN CAS Find my …

Gold-catalyzed synthesis of benzil derivatives and α-keto imides via oxidation of alkynes

CF Xu, M Xu, YX Jia, CY Li - Organic Letters, 2011‏ - ACS Publications
An efficient process based on the gold-catalyzed redox reaction has been developed to
oxidize 1, 2-diarylacetylene or ynamide to 1, 2-diaryldiketone or α-keto imide respectively …

General amination reactions for the synthesis of ynamides

G Evano, K Jouvin, A Coste - Synthesis, 2013‏ - thieme-connect.com
The development of general syntheses of ynamides and related compounds based on
various amination strategies are described in this short review. Reactions are classified …

Highly regioselective Au (I)-catalyzed hydroamination of ynamides and propiolic acid derivatives with anilines

S Kramer, K Dooleweerdt, AT Lindhardt… - Organic …, 2009‏ - ACS Publications
A highly regioselective hydroamination of unsymmetrical electron-poor and electron-rich
alkynes with anilines catalyzed by Au (I) under mild conditions is reported. In addition …

A robust and modular synthesis of ynamides

SJ Mansfield, CD Campbell, MW Jones… - Chemical …, 2015‏ - pubs.rsc.org
A flexible, modular ynamide synthesis is reported that uses trichloroethene as an
inexpensive two carbon synthon. A wide range of amides and electrophiles can be …

Sequential and One-Pot Reactions of Phenols with Bromoalkynes for the Synthesis of (Z)-2-Bromovinyl Phenyl Ethers and Benzo[b]furans

S Wang, P Li, L Yu, L Wang - Organic Letters, 2011‏ - ACS Publications
Benzo [b] furans were prepared in one pot based on the addition/palladium-catalyzed C–H
bond functionalization of phenols with bromoalkynes. The addition reactions of phenols to …