The rise and current status of polaritonic photochemistry and photophysics

R Bhuyan, J Mony, O Kotov, GW Castellanos… - Chemical …, 2023 - ACS Publications
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Theoretical challenges in polaritonic chemistry

J Fregoni, FJ Garcia-Vidal, J Feist - ACS photonics, 2022 - ACS Publications
Polaritonic chemistry exploits strong light–matter coupling between molecules and confined
electromagnetic field modes to enable new chemical reactivities. In systems displaying this …

Experimental characterization techniques for plasmon-assisted chemistry

E Cortés, R Grzeschik, SA Maier… - Nature Reviews …, 2022 - nature.com
Plasmon-assisted chemistry is the result of a complex interplay between electromagnetic
near fields, heat and charge transfer on the nanoscale. The disentanglement of their roles is …

[HTML][HTML] Advances in ultrafast plasmonics

AN Koya, M Romanelli, J Kuttruff… - Applied Physics …, 2023 - pubs.aip.org
In the past 20 years, we have reached a broad understanding of many light-driven
phenomena in nanoscale systems. The temporal dynamics of the excited states are instead …

Recent developments in plasmonic alloy nanoparticles: synthesis, modelling, properties and applications

V Coviello, D Forrer, V Amendola - ChemPhysChem, 2022 - Wiley Online Library
Despite the traditional plasmonic materials are counted on one hand, there are a lot of
possible combinations leading to alloys with other elements of the periodic table, in …

Catalysis by dark states in vibropolaritonic chemistry

M Du, J Yuen-Zhou - Physical Review Letters, 2022 - APS
Collective strong coupling between a disordered ensemble of N localized molecular
vibrations and a resonant optical cavity mode gives rise to two polariton and N-1≫ 2 dark …

Peeking into the femtosecond hot-carrier dynamics reveals unexpected mechanisms in plasmonic photocatalysis

G Dall'Osto, M Marsili, M Vanzan, D Toffoli… - Journal of the …, 2024 - ACS Publications
Plasmonic-driven photocatalysis may lead to reaction selectivity that cannot be otherwise
achieved. A fundamental role is played by hot carriers, ie, electrons and holes generated …

[HTML][HTML] Hybrid QM/classical models: Methodological advances and new applications

F Lipparini, B Mennucci - Chemical Physics Reviews, 2021 - pubs.aip.org
Hybrid methods that combine quantum mechanical descriptions with classical models are
very popular in molecular modeling. Such a large diffusion reflects their effectiveness, which …

A vision for the future of multiscale modeling

M Capone, M Romanelli, D Castaldo… - ACS Physical …, 2024 - ACS Publications
The rise of modern computer science enabled physical chemistry to make enormous
progresses in understanding and harnessing natural and artificial phenomena …