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The rise and current status of polaritonic photochemistry and photophysics
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
Molecular polaritonics: Chemical dynamics under strong light–matter coupling
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …
intense experimental and theoretical studies. Here we review the present status of this field …
Theoretical challenges in polaritonic chemistry
Polaritonic chemistry exploits strong light–matter coupling between molecules and confined
electromagnetic field modes to enable new chemical reactivities. In systems displaying this …
electromagnetic field modes to enable new chemical reactivities. In systems displaying this …
Experimental characterization techniques for plasmon-assisted chemistry
Plasmon-assisted chemistry is the result of a complex interplay between electromagnetic
near fields, heat and charge transfer on the nanoscale. The disentanglement of their roles is …
near fields, heat and charge transfer on the nanoscale. The disentanglement of their roles is …
[HTML][HTML] Advances in ultrafast plasmonics
In the past 20 years, we have reached a broad understanding of many light-driven
phenomena in nanoscale systems. The temporal dynamics of the excited states are instead …
phenomena in nanoscale systems. The temporal dynamics of the excited states are instead …
Recent developments in plasmonic alloy nanoparticles: synthesis, modelling, properties and applications
Despite the traditional plasmonic materials are counted on one hand, there are a lot of
possible combinations leading to alloys with other elements of the periodic table, in …
possible combinations leading to alloys with other elements of the periodic table, in …
Catalysis by dark states in vibropolaritonic chemistry
Collective strong coupling between a disordered ensemble of N localized molecular
vibrations and a resonant optical cavity mode gives rise to two polariton and N-1≫ 2 dark …
vibrations and a resonant optical cavity mode gives rise to two polariton and N-1≫ 2 dark …
Peeking into the femtosecond hot-carrier dynamics reveals unexpected mechanisms in plasmonic photocatalysis
Plasmonic-driven photocatalysis may lead to reaction selectivity that cannot be otherwise
achieved. A fundamental role is played by hot carriers, ie, electrons and holes generated …
achieved. A fundamental role is played by hot carriers, ie, electrons and holes generated …
[HTML][HTML] Hybrid QM/classical models: Methodological advances and new applications
Hybrid methods that combine quantum mechanical descriptions with classical models are
very popular in molecular modeling. Such a large diffusion reflects their effectiveness, which …
very popular in molecular modeling. Such a large diffusion reflects their effectiveness, which …
A vision for the future of multiscale modeling
The rise of modern computer science enabled physical chemistry to make enormous
progresses in understanding and harnessing natural and artificial phenomena …
progresses in understanding and harnessing natural and artificial phenomena …