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Ultrastable glasses: new perspectives for an old problem
Ultrastable glasses (mostly prepared from the vapor phase under optimized deposition
conditions) represent a unique class of materials with low enthalpies and high kinetic …
conditions) represent a unique class of materials with low enthalpies and high kinetic …
Ultrastable glasses from in silico vapour deposition
Glasses are generally prepared by cooling from the liquid phase, and their properties
depend on their thermal history. Recent experiments indicate that glasses prepared by …
depend on their thermal history. Recent experiments indicate that glasses prepared by …
Structural relaxation of vapor-deposited molecular glasses and supercooled liquids
K Ishii, H Nakayama - Physical Chemistry Chemical Physics, 2014 - pubs.rsc.org
Molecular glasses prepared by vapor deposition have been revealed in recent years to have
properties which the glasses prepared by ordinary liquid-quenching methods do not have …
properties which the glasses prepared by ordinary liquid-quenching methods do not have …
Emergence of equilibrated liquid regions within the glass
The conventional understanding of the glass transition is that the transition from glass to
liquid appears as a dynamic process in which atoms or molecules relax cooperatively into …
liquid appears as a dynamic process in which atoms or molecules relax cooperatively into …
Stability of thin film glasses of toluene and ethylbenzene formed by vapor deposition: an in situ nanocalorimetric study
Vapor deposited thin films (∼ 100 nm thickness) of toluene and ethylbenzene grown by
physical vapor deposition show enhanced stability with respect to samples slowly cooled …
physical vapor deposition show enhanced stability with respect to samples slowly cooled …
Model vapor-deposited glasses: Growth front and composition effects
A growing body of experimental work indicates that physical vapor deposition provides an
effective route for preparation of stable glasses, whose properties correspond in some cases …
effective route for preparation of stable glasses, whose properties correspond in some cases …
Structural signatures of ultrastability in a deposited glassformer
Glasses obtained from vapor deposition on a cold substrate have superior thermodynamic
and kinetic stability with respect to ordinary glasses. Here we perform molecular dynamics …
and kinetic stability with respect to ordinary glasses. Here we perform molecular dynamics …
A molecular view of vapor deposited glasses
Recently, novel organic glassy materials that exhibit remarkable stability have been
prepared by vapor deposition. The thermophysical properties of these new “stable” glasses …
prepared by vapor deposition. The thermophysical properties of these new “stable” glasses …
Macroscopic facilitation of glassy relaxation kinetics: Ultrastable glass films with frontlike thermal response
S Léonard, P Harrowell - The Journal of chemical physics, 2010 - pubs.aip.org
The recent experimental fabrication of ultrastable glass films, via vapor deposition [Swallen
et al., Science 315, 353 (2007)] and the observation of frontlike response to the annealing of …
et al., Science 315, 353 (2007)] and the observation of frontlike response to the annealing of …
Self-diffusion of supercooled tris-naphthylbenzene
SF Swallen, K Traynor, RJ McMahon… - The Journal of …, 2009 - ACS Publications
We have measured self-diffusion coefficients for deeply supercooled tris-naphthylbenzene
using secondary ion mass spectrometry. Isotopically labeled multilayer films were prepared …
using secondary ion mass spectrometry. Isotopically labeled multilayer films were prepared …