This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Bis (oxazolines) are a well-known class of ligands in the area of asymmetric catalysis. Most
of these ligands are C 2-symmetric due to the synthetic route employed for their synthesis …

A series of five-membered N-heterocyclic carbene C, S palladium (II) π-allyl complexes were
successfully developed and characterized. Structural analyses of these complexes revealed …

A new approach to the synthesis of Tekturna, a recently marketed drug for hypertension,
takes advantage of a modified protocol of the Stoltz palladium-catalyzed asymmetric …

A C1-symmetric Box macrocycle has been synthesized for the first time. The Box macrocycle
along with other C1 and C2-symmetric Box ligands were evaluated and compared as …

A practical one-pot method for the synthesis of biimidazoline has been developed. A variety
of biimidazolines were prepared smoothly under mild conditions and were evaluated in Pd …

Abstract A novel Pd/1, 2-diphosphite catalyzed asymmetric allylic alkylation of 1, 3-
diarylpropenyl acetate with malonates was developed. Catalyst optimization via a variation …

A new class of highly stable O, N, N, O-tetradentate bioxazoline ligands were synthesized
from l-tartaric acid. Exploration of those ligands in Pd-catalyzed asymmetric allylic alkylation …

Tartrate‐derived bioxazoline ligands, which form a five‐membered chelate ring with metals,
were evaluated for use in the asymmetric allylic alkylation (AAA) reactions of various …

Allylic substitution is recognized as one of the most powerful tools in organic synthesis for
the construction of CC and C-heteroatom bonds. The best-known example is the Tsuji-Trost …