Polymers of intrinsic microporosity for membrane-based precise separations

X Feng, J Zhu, J **, Y Wang, Y Zhang… - Progress in Materials …, 2024 - Elsevier
Polymer materials have been extensively utilized in diverse separation fields, especially in
membrane-based nanotechnologies for gas and liquid separations. The membrane …

Gas permeation properties, physical aging, and its mitigation in high free volume glassy polymers

ZX Low, PM Budd, NB McKeown… - Chemical reviews, 2018 - ACS Publications
Hundreds of polymers have been evaluated as membrane materials for gas separations, but
fewer than 10 have made it into current commercial applications, mainly due to the effects of …

Polyimides in membrane gas separation: Monomer's molecular design and structural engineering

H Sanaeepur, AE Amooghin, S Bandehali… - Progress in Polymer …, 2019 - Elsevier
Polyimides (PIs) are an important, well-established, and commercialized class of polymers
due to their extraordinary physical and chemical properties. They have been extensively …

Advances in high permeability polymer-based membrane materials for CO 2 separations

S Wang, X Li, H Wu, Z Tian, Q **n, G He… - Energy & …, 2016 - pubs.rsc.org
Membrane processes have evolved as a competitive approach in CO2 separations
compared with absorption and adsorption processes, due to their inherent attributes such as …

[HTML][HTML] Polyimides containing aliphatic/alicyclic segments in the main chains

Y Zhuang, JG Seong, YM Lee - Progress in Polymer Science, 2019 - Elsevier
Abstract Aliphatic/alicyclic (Al)-containing polyimides (PIs), including fully-Al-PIs and partially-
Al-PIs, are widely employed in electric, electronics, optical materials, and other advanced …

Penetrant-induced plasticization in microporous polymer membranes

KM Rodriguez, S Lin, AX Wu, KR Storme… - Chemical Society …, 2024 - pubs.rsc.org
Penetrant-induced plasticization has prevented the industrial deployment of many polymers
for membrane-based gas separations. With the advent of microporous polymers, new …

[HTML][HTML] Polymers of intrinsic microporosity for energy-intensive membrane-based gas separations

Y Wang, X Ma, BS Ghanem, F Alghunaimi, I Pinnau… - Materials Today …, 2018 - Elsevier
This review provides a new perspective on the role of the state-of-the-art polymers of
intrinsic microporosity (PIMs) in key energy-intensive membrane-based gas separations …

Fine-tuned intrinsically ultramicroporous polymers redefine the permeability/selectivity upper bounds of membrane-based air and hydrogen separations

R Swaidan, B Ghanem, I Pinnau - 2015 - ACS Publications
Intrinsically ultramicroporous (< 7 Å) polymers represent a new paradigm in materials
development for membrane-based gas separation. In particular, they demonstrate that …

Membrane-based carbon capture technologies: Membrane gas separation vs. membrane contactor

UWR Siagian, A Raksajati, NF Himma… - Journal of Natural Gas …, 2019 - Elsevier
In this paper, the recent development of membrane-based carbon capture technologies is
reviewed, including membrane gas separation (MGS) and membrane contactor (MC). The …

Physical aging, plasticization and their effects on gas permeation in “rigid” polymers of intrinsic microporosity

R Swaidan, B Ghanem, E Litwiller, I Pinnau - Macromolecules, 2015 - ACS Publications
Long-term physical aging and plasticization, two mobility-based phenomena that are
counterintuitive in the context of “rigid” polymers of intrinsic microporosity (PIMs), were …