Beyond a solvent: triple roles of dimethylformamide in organic chemistry
N, N-Dimethylformamide (DMF) is frequently used as an aprotic solvent in chemical
transformations in laboratories of academia as well as in those of chemical industry. In the …
transformations in laboratories of academia as well as in those of chemical industry. In the …
A perspective on heterogeneous catalysts for the selective oxidation of alcohols
S Najafishirtari, K Friedel Ortega… - … A European Journal, 2021 - Wiley Online Library
Selective oxidation of higher alcohols using heterogeneous catalysts is an important
reaction in the synthesis of fine chemicals with added value. Though the process for primary …
reaction in the synthesis of fine chemicals with added value. Though the process for primary …
Chemical upcycling of commodity thermoset polyurethane foams towards high-performance 3D photo-printing resins
Z Liu, Z Fang, N Zheng, K Yang, Z Sun, S Li, W Li… - Nature Chemistry, 2023 - nature.com
Polyurethane thermosets are indispensable to modern life, but their widespread use has
become an increasingly pressing environmental burden. Current recycling approaches are …
become an increasingly pressing environmental burden. Current recycling approaches are …
Highly Efficient Ruthenium‐Catalyzed N‐Formylation of Amines with H2 and CO2
L Zhang, Z Han, X Zhao, Z Wang… - Angewandte Chemie …, 2015 - Wiley Online Library
A highly efficient catalyst system based on ruthenium‐pincer‐type complexes has been
discovered for N‐formylation of various amines with CO2 and H2, thus affording the …
discovered for N‐formylation of various amines with CO2 and H2, thus affording the …
Reductive functionalization of CO 2 with amines: an entry to formamide, formamidine and methylamine derivatives
CO2 utilization for the production of C1-containing molecules is a desirable route to value-
added chemicals. In this perspective, we summarize the recent results devoted to the …
added chemicals. In this perspective, we summarize the recent results devoted to the …
Self-sacrificed synthesis of three-dimensional Na3V2 (PO4) 3 nanofiber network for high-rate sodium–ion full batteries
The morphological optimization of Na 3 V 2 (PO 4) 3 (NVP) material has a great significance
for improving the electrochemical performance since NVP suffers from intrinsic low …
for improving the electrochemical performance since NVP suffers from intrinsic low …
Self-sacrificed synthesis of conductive vanadium-based metal–organic framework nanowire-bundle arrays as binder-free cathodes for high-rate and high-energy …
Metal-organic frameworks (MOFs) with adjustable structures and large surface areas are
attracting ever-increasing attention in the field of next-generation energy storage. However …
attracting ever-increasing attention in the field of next-generation energy storage. However …
Cobalt‐catalyzed C H cyanation of arenes and heteroarenes
J Li, L Ackermann - Angewandte Chemie, 2015 - Wiley Online Library
Carboxylate assistance proved to be the key for the success of efficient cobalt (III)‐catalyzed
C H cyanations. Thus, an in situ generated cationic cobalt complex was identified as a …
C H cyanations. Thus, an in situ generated cationic cobalt complex was identified as a …
Direct Aerobic Carbonylation of C(sp2)–H and C(sp3)–H Bonds through Ni/Cu Synergistic Catalysis with DMF as the Carbonyl Source
X Wu, Y Zhao, H Ge - Journal of the American Chemical Society, 2015 - ACS Publications
The direct carbonylation of aromatic sp2 and unactivated sp3 C–H bonds of amides was
achieved via nickel/copper catalysis under atmospheric O2 with the assistance of a …
achieved via nickel/copper catalysis under atmospheric O2 with the assistance of a …
Increasing the reactivity of amides towards organometallic reagents: an overview
The nucleophilic addition of carbon nucleophiles to amides has traditionally been a difficult
task, both due to reactivity and selectivity problems. When successful, these processes …
task, both due to reactivity and selectivity problems. When successful, these processes …