Revealing key structural features hidden in liquids and glasses
A great success of solid state physics comes from the characterization of crystal structures in
the reciprocal (wave vector) space. The power of structural characterization in Fourier space …
the reciprocal (wave vector) space. The power of structural characterization in Fourier space …
Advances in computational studies of the liquid–liquid transition in water and water-like models
There has been uninterrupted interest in supercooled water ever since the pioneering
experiments of Speedy and Angell revealed sharp increases in this substance's response …
experiments of Speedy and Angell revealed sharp increases in this substance's response …
The anomalies and criticality of liquid water
The origin of water's anomalies has been a matter of long-standing debate. A two-state
model, dating back to Röntgen, relies on the dynamical coexistence of two types of local …
model, dating back to Röntgen, relies on the dynamical coexistence of two types of local …
Reversible structural transformations in supercooled liquid water from 135 to 245 K
A fundamental understanding of the unusual properties of water remains elusive because of
the limited data at the temperatures and pressures needed to decide among competing …
the limited data at the temperatures and pressures needed to decide among competing …
Common microscopic structural origin for water's thermodynamic and dynamic anomalies
Water displays a vast array of unique properties, known as water's anomalies, whose origin
remains subject to hot debate. Our aim in this article is to provide a unified microscopic …
remains subject to hot debate. Our aim in this article is to provide a unified microscopic …
Perspective: Crossing the Widom line in no man's land: Experiments, simulations, and the location of the liquid-liquid critical point in supercooled water
NJ Hestand, JL Skinner - The Journal of Chemical Physics, 2018 - pubs.aip.org
The origin of liquid water's anomalous behavior continues to be a subject of interest and
debate. One possible explanation is the liquid-liquid critical point hypothesis, which …
debate. One possible explanation is the liquid-liquid critical point hypothesis, which …
Coherent X-rays reveal the influence of cage effects on ultrafast water dynamics
The dynamics of liquid water feature a variety of time scales, ranging from extremely fast
ballistic-like thermal motion, to slower molecular diffusion and hydrogen-bond …
ballistic-like thermal motion, to slower molecular diffusion and hydrogen-bond …
[HTML][HTML] Comment on “The putative liquid-liquid transition is a liquid-solid transition in atomistic models of water”[I and II: J. Chem. Phys. 135, 134503 (2011); J. Chem …
Limmer and Chandler's (LC) calculations for the ST2 model of water 1, 2 show evidence of
only a single metastable liquid at conditions where other studies 3–6 report a liquid-liquid …
only a single metastable liquid at conditions where other studies 3–6 report a liquid-liquid …
Vibrational spectroscopy of water with high spatial resolution
JR Jokisaari, JA Hachtel, X Hu, A Mukherjee… - Advanced …, 2018 - Wiley Online Library
The ability to examine the vibrational spectra of liquids with nanometer spatial resolution will
greatly expand the potential to study liquids and liquid interfaces. In fact, the fundamental …
greatly expand the potential to study liquids and liquid interfaces. In fact, the fundamental …
Probing the OH stretch in different local environments in liquid water
We use resonant inelastic X-ray scattering (RIXS) to resolve vibrational losses
corresponding to the OH stretch where the X-ray absorption process allows us to selectively …
corresponding to the OH stretch where the X-ray absorption process allows us to selectively …