Metal–organic network-forming glasses

N Ma, S Horike - Chemical Reviews, 2022 - ACS Publications
The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …

Metal-organic framework as a photocatalyst: Progress in modulation strategies and environmental/energy applications

SA Younis, EE Kwon, M Qasim, KH Kim, T Kim… - Progress in Energy and …, 2020 - Elsevier
Progress in the design, synthesis, and modification of metal-organic frameworks (MOFs) has
immensely helped expand their applications in a wide variety of research fields. Such …

Understanding glass through differential scanning calorimetry

Q Zheng, Y Zhang, M Montazerian, O Gulbiten… - Chemical …, 2019 - ACS Publications
Differential scanning calorimetry (DSC) is a powerful tool to address some of the most
challenging issues in glass science and technology, such as the nonequilibrium nature of …

Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture

AJ Rieth, AM Wright, M Dincă - Nature Reviews Materials, 2019 - nature.com
Metal–organic frameworks (MOFs) have diverse applications involving the storage,
separation and sensing of weakly interacting, high-purity gases. Exposure to impure gas …

A new dimension for coordination polymers and metal–organic frameworks: towards functional glasses and liquids

S Horike, SS Nagarkar, T Ogawa… - Angewandte Chemie …, 2020 - Wiley Online Library
There are two categories of coordination polymers (CPs): inorganic CPs (i‐CPs) and organic
ligand bridged CPs (o‐CPs). Based on the successful crystal engineering of CPs, we here …

Fracture toughness of a metal–organic framework glass

T To, SS Sørensen, M Stepniewska, A Qiao… - Nature …, 2020 - nature.com
Metal-organic framework glasses feature unique thermal, structural, and chemical properties
compared to traditional metallic, organic, and oxide glasses. So far, there is a lack of …

ResponZIF structures: zeolitic imidazolate frameworks as stimuli-responsive materials

P Iacomi, G Maurin - ACS Applied Materials & Interfaces, 2021 - ACS Publications
Zeolitic imidazolate frameworks (ZIFs) have long been recognized as a prominent subset of
the metal–organic framework (MOF) family, in part because of their ease of synthesis and …

Functions and applications of emerging metal–organic-framework liquids and glasses

M Wang, H Zhao, B Du, X Lu, S Ding… - Chemical …, 2023 - pubs.rsc.org
Traditional metal–organic-frameworks (MOFs) have been extensively studied and applied in
various fields across chemistry, biology and engineering in the past decades. Recently, a …

Observation of indentation-induced shear bands in a metal− organic framework glass

M Stepniewska, K Januchta, C Zhou… - Proceedings of the …, 2020 - National Acad Sciences
Metal− organic framework (MOF) glasses are a newly emerged family of melt-quenched
glasses. Recently, several intriguing features, such as ultrahigh glass-forming ability and low …

Metal–organic framework glasses possess higher thermal conductivity than their crystalline counterparts

SS Sørensen, MB Østergaard… - … applied materials & …, 2020 - ACS Publications
The thermal conductivity (κ) of glasses is known to always be lower than that of their
corresponding crystals due to the stronger phonon–phonon scattering in the former …