Chemical diversity for tailoring negative thermal expansion

Q Li, K Lin, Z Liu, L Hu, Y Cao, J Chen… - Chemical Reviews, 2022 - ACS Publications
Negative thermal expansion (NTE), referring to the lattice contraction upon heating, has
been an attractive topic of solid-state chemistry and functional materials. The response of a …

Negative thermal expansion in framework structure materials

N Shi, Y Song, X **ng, J Chen - Coordination Chemistry Reviews, 2021 - Elsevier
Negative thermal expansion (NTE) is a counterintuitive physical phenomenon that the unit
cell volume of material usually contracts instead of expands upon heating. With two …

Responsive metal–organic frameworks and framework materials: under pressure, taking the heat, in the spotlight, with friends

FX Coudert - Chemistry of Materials, 2015 - ACS Publications
Recent years have seen a large increase of the research effort focused on framework
materials, including the nowadays-ubiquitous metal–organic frameworks but also dense …

Controlling flexibility of metal–organic frameworks

JP Zhang, HL Zhou, DD Zhou, PQ Liao… - National Science …, 2018 - academic.oup.com
Abstract Framework flexibility is one of the most important characteristics of metal–organic
frameworks (MOFs), which is not only interesting, but also useful for a variety of applications …

Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers

JP Zhang, PQ Liao, HL Zhou, RB Lin… - Chemical Society …, 2014 - pubs.rsc.org
X-Ray single-crystal diffraction has been the most straightforward and important technique in
structural determination of crystalline materials for understanding their structure–property …

Negative thermal expansion materials: technological key for control of thermal expansion

K Takenaka - Science and technology of advanced materials, 2012 - iopscience.iop.org
Most materials expand upon heating. However, although rare, some materials contract upon
heating. Such negative thermal expansion (NTE) materials have enormous industrial merit …

Negative thermal expansion and associated anomalous physical properties: review of the lattice dynamics theoretical foundation

MT Dove, H Fang - Reports on Progress in Physics, 2016 - iopscience.iop.org
Negative thermal expansion (NTE) is the phenomenon in which materials shrink rather than
expand on heating. Although NTE had been previously observed in a few simple materials …

[BOEK][B] Coordination polymers: design, analysis and application

SR Batten, SM Neville, DR Turner - 2008 - books.google.com
The field of coordination polymer research has undergone rapid expansion in recent years.
No longer are these materials the vaguely defined'insoluble material'at the bottom of your …

Progress of research in negative thermal expansion materials: paradigm shift in the control of thermal expansion

K Takenaka - Frontiers in chemistry, 2018 - frontiersin.org
To meet strong demands for the control of thermal expansion necessary because of the
advanced development of industrial technology, widely various giant negative thermal …

Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF3

BK Greve, KL Martin, PL Lee, PJ Chupas… - Journal of the …, 2010 - ACS Publications
Scandium trifluoride maintains a cubic ReO3 type structure down to at least 10 K, although
the pressure at which its cubic to rhombohedral phase transition occurs drops from> 0.5 GPa …