Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-
titanium clusters (PTCs) have been closely related to many photo-activities that broadly …

A series of catecholate-functionalized titanium-oxo clusters (TOCs), PTC-271 to PTC-277,
with atomically precise structures were synthesized and characterized, including distinctive …

Conspectus Atomically precise titanium-oxo clusters (TOCs) are the structure and reactivity
model compounds of technically important TiO2 materials, which could help build structure …

The synthesis of hollow opening polyhedral cages has always been an attractive but
challenging goal, especially with regard to inorganic polyhedral cages. Herein, we present a …

Searching for suitable methods to construct all-inorganic cage materials by using
polyoxometalates (POMs) as secondary building units (SBUs) has been of great interest …

Buckminsterfullerene (C60) represents a perfect combination of geometry and molecular
structural chemistry. It has inspired many creative ideas for building fullerene-like …

We report a 3.6 nm Ti52–oxo cluster with precise atomic structure, which presents a largest
size record in the family of titanium–oxo clusters (TOCs). The crystal growth of such large …

Phase isomerism is a common and important phenomenon in inorganic materials, but the
molecular isomerism of their nanocluster models is still rare. In this work, we report the first …

Thin film materials have been used widely in semiconductor devices, including solar cells,
transistors, light emitting diodes, light crystal displays, smart windows, chips as well as …