Supramolecular Assembly Frameworks (SAFs): Sha** the Future of Functional Materials

X Tang, J Pang, J Dong, Y Liu, XH Bu… - Angewandte Chemie …, 2024 - Wiley Online Library
Supramolecular assembly frameworks (SAFs) represent a new category of porous materials,
utilizing non‐covalent interactions, setting them apart from metal–organic frameworks …

Metal-organic frameworks: Recent advances in synthesis strategies and applications

RU Rajesh, T Mathew, H Kumar, A Singhal… - Inorganic Chemistry …, 2024 - Elsevier
Metal-organic frameworks (MOFs) are cage-like structures composed of metal ions
surrounded by organic linkers. Arms of linkers contain metal ions giving the characteristic …

Anion Modulation of Ag‐Imidazole Cuboctahedral Cage Microenvironments for Efficient Electrocatalytic CO2 Reduction

W Yang, Q Mo, QT He, XP Li, Z Xue… - Angewandte Chemie …, 2024 - Wiley Online Library
How to achieve CO2 electroreduction in high efficiency is a current challenge with the
mechanism not well understood yet. The metal‐organic cages with multiple metal sites …

sp2-c linked Cu-based metal-covalent organic framework for chemical and photocatalysis synergistic reduction of uranium

JL Liu, MX Lin, J Huang, CR Zhang, JX Qi… - Chemical Engineering …, 2024 - Elsevier
The reduction of hexavalent uranium to tetravalent uranium is an effective strategy for
controlling uranium contamination in wastewater. Herein, a Cdouble bondC bonded metal …

Geometric tuning of coordinatively unsaturated copper (I) sites in metal–organic frameworks for ambient-temperature hydrogen storage

Y Yabuuchi, H Furukawa, KM Carsch… - Journal of the …, 2024 - ACS Publications
Porous solids can accommodate and release molecular hydrogen readily, making them
attractive for minimizing the energy requirements for hydrogen storage relative to physical …

Fine-tuned MOF-74 type variants with open metal sites for high volumetric hydrogen storage at near-ambient temperature

DW Kim, M Jung, DY Shin, N Kim, J Park… - Chemical Engineering …, 2024 - Elsevier
Adsorbent-based hydrogen storage systems offer a potential solution to current challenges
in hydrogen storage, particularly those requiring high pressures or cryogenic temperatures …

High Hydrogen Storage in Trigonal Prismatic Monomer‐Based Highly Porous Aromatic Frameworks

DW Kim, Y Chen, H Kim, N Kim, YH Lee… - Advanced …, 2024 - Wiley Online Library
Hydrogen storage is crucial in the shift toward a carbon‐neutral society, where hydrogen
serves as a pivotal renewable energy source. Utilizing porous materials can provide an …

Polymer-coated covalent organic frameworks as porous liquids for gas storage

RE Mow, GA Russell-Parks, GEB Redwine… - Chemistry of …, 2024 - ACS Publications
Several synthetic methods have recently emerged to develop high-surface-area solid-state
organic framework-based materials into free-flowing liquids with permanent porosity. The …

Integrated CO2 Capture and Conversion by a Robust Cu(I)-Based Metal–Organic Framework

D Sengupta, S Bose, X Wang… - Journal of the …, 2024 - ACS Publications
Metal–organic frameworks (MOFs) have shown promise in both capturing CO2 under flue
gas conditions and converting it into valuable chemicals. However, the development of a …

Investigation of Anionic Metal–Organic Frameworks with Extra-Framework Cations for Room Temperature Hydrogen Storage

TD Pham, D Sengupta, OK Farha… - Chemistry of …, 2024 - ACS Publications
Hydrogen (H2) is a clean alternative to fossil fuels and can be produced by using renewable
energy sources. However, due to its low volumetric energy density, H2 storage requires low …