Conspectus Transition-metal-catalyzed reductive coupling of electrophiles has emerged as
a powerful tool for the construction of molecules. While major achievements have been …

Cross-electrophile coupling (XEC), defined by us as the cross-coupling of two different σ-
electrophiles that is driven by catalyst reduction, has seen rapid progression in recent years …

The asymmetric cross-coupling of unsaturated bonds, hampered by their comparable
polarity and reactivity, as well as the scarcity of efficient catalytic systems capable of …

Direct decarboxylative alkenylation of widely available aliphatic carboxylic acids with vinyl
halides for the synthesis of alkenes with all substitution patterns has been accomplished by …

Given the abundance of alcohol feedstocks and the significance of disulfides, we herein
report a nickel-catalyzed direct deoxygenative disulfuration of alcohols with trisulfide …

Transition-metal-catalyzed reductive cross-coupling reactions have been developed as one
of the important tools for constructing C–C bonds. These reactions involve the direct …

Catalytic transformation of alcohols via metal-catalyzed cross-coupling reactions is very
important, but it typically relies on a multistep procedure. We here report a dynamic kinetic …

Cobalt complexes of chiral pyrox ligands catalyzed enantioselective reductive couplings of
nonconjugated iododienes with aryl iodides or alkenyl bromides. The reaction enabled …

We report here a new method for the synthesis of organohydrosilanes from phenols and
ketones. This method is established through reductive C− Si coupling of chlorohydrosilanes …

A straightforward cross-coupling of aryl thioether with aryl bromide with the aid of nickel salt,
magnesium, and lithium chloride in tetrahydrofuran at ambient temperature was …