Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Control, modulation, and analytical descriptions of vibrational strong coupling

BS Simpkins, AD Dunkelberger, I Vurgaftman - Chemical Reviews, 2023 - ACS Publications
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …

Modification of ground-state chemical reactivity via light–matter coherence in infrared cavities

W Ahn, JF Triana, F Recabal, F Herrera, BS Simpkins - Science, 2023 - science.org
Reaction-rate modifications for chemical processes due to strong coupling between reactant
molecular vibrations and the cavity vacuum have been reported; however, no currently …

Chemistry under vibrational strong coupling

K Nagarajan, A Thomas… - Journal of the American …, 2021 - ACS Publications
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

[HTML][HTML] Molecular polaritons for controlling chemistry with quantum optics

F Herrera, J Owrutsky - The Journal of chemical physics, 2020 - pubs.aip.org
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic
physical principles and consequences of strong light–matter coupling common to molecular …

Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry

JA Campos-Gonzalez-Angulo, YR Poh, M Du… - The Journal of …, 2023 - pubs.aip.org
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …

Relevance of the quadratic diamagnetic and self-polarization terms in cavity quantum electrodynamics

C Schäfer, M Ruggenthaler, V Rokaj, A Rubio - ACS photonics, 2020 - ACS Publications
Experiments at the interface of quantum optics and chemistry have revealed that strong
coupling between light and matter can substantially modify the chemical and physical …

Quantum information and algorithms for correlated quantum matter

K Head-Marsden, J Flick, CJ Ciccarino… - Chemical …, 2020 - ACS Publications
Discoveries in quantum materials, which are characterized by the strongly quantum-
mechanical nature of electrons and atoms, have revealed exotic properties that arise from …