Formal Total Syntheses of (−)-and (+)-Actinophyllic Acid

F Xue, H Lu, L He, W Li, D Zhang… - The Journal of Organic …, 2018 - ACS Publications
The formal total syntheses of (−)-actinophyllic acid and its enantiomer starting from the same
chiral intermediate are reported. The synthesis features a photoredox organocatalytic …

Metal‐Free Oxyacetoxylation of Arylynamines and Ynamides To Construct α‐Acetoxyl Amides

R Long, S Huang, HK Wu, N Iqbal… - European Journal of …, 2023 - Wiley Online Library
Ynamides/arylynamines are challenging substrates for oxyacetoxylation, especially due to
various reactive sites of the N‐heteroaryl ring. Herein, we report a metal‐free PhI (OAc) 2 …

Total Synthesis of Actinophyllic Acid

Y Yoshii, H Tokuyama… - Angewandte Chemie …, 2017 - Wiley Online Library
Herein we report a total synthesis of the indolohydroazocine natural product actinophyllic
acid. The target molecule was retrosynthetically deconvoluted to render a greatly simplified …

Facile conversion of α‐acyloxy amides into 3‐hydroxy‐lactams

D Koszelewski, D Trzepizur, E Zaorska… - European Journal of …, 2018 - Wiley Online Library
The new synthetic route to α‐acyloxy amides based on Passerini multicomponent reaction
followed by transformation into the corresponding five‐, six‐, and seven‐membered 3 …

A Facile Synthesis of N-Boc-azocan-5-one

M Morales-Chamorro, A Vázquez - Synthesis, 2019 - thieme-connect.com
The azacycloalkane 1-azocan-5-one is embedded in the structure of several products of
natural origin displaying a variety of bioactivities. Two convenient and straightforward routes …

Total Synthesis of Ervatamia Alkaloids

P Gamerdinger - 2023 - kops.uni-konstanz.de
This work discusses an enantioselective total synthesis of Ervatamia alkaloids. It relies on an
enzyme-catalyzed desymmetrization approach for the installation of chirality. The indole …