Strategies for accessing photosensitizers with extreme redox potentials
Photoredox catalysis has been prominent in many applications, including solar fuels,
organic synthesis, and polymer chemistry. Photocatalytic activity directly depends on the …
organic synthesis, and polymer chemistry. Photocatalytic activity directly depends on the …
Non-covalent intramolecular interactions through ligand-design promoting efficient photoluminescence from transition metal complexes
Ligand design allows arranging ligand entities and functional groups in order to generate a
plethora of non-covalent interactions such as π stacking, H bridging, and Lewis acid-base …
plethora of non-covalent interactions such as π stacking, H bridging, and Lewis acid-base …
Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel (II) Complexes
Square-planar NiII complexes and their electronically excited states play key roles in cross-
coupling catalysis and could offer new opportunities to complement well-known …
coupling catalysis and could offer new opportunities to complement well-known …
High triplet energy iridium (III) isocyanoborato complex for photochemical upconversion, photoredox and energy transfer catalysis
L Schmid, F Glaser, R Schaer… - Journal of the American …, 2022 - ACS Publications
Cyclometalated Ir (III) complexes are often chosen as catalysts for challenging photoredox
and triplet–triplet-energy-transfer (TTET) catalyzed reactions, and they are of interest for …
and triplet–triplet-energy-transfer (TTET) catalyzed reactions, and they are of interest for …
High‐Sulfur Loading and Single Ion‐Selective Membranes for High‐Energy and Durable Decoupled Aqueous Batteries
The decoupled battery design is promising for breaking the energy density limit of traditional
aqueous batteries. However, the complex battery configuration and low‐selective separator …
aqueous batteries. However, the complex battery configuration and low‐selective separator …
Photostable ruthenium (II) isocyanoborato luminophores and their use in energy transfer and photoredox catalysis
Ruthenium (II) polypyridine complexes are among the most popular sensitizers in
photocatalysis, but they face some severe limitations concerning accessible excited-state …
photocatalysis, but they face some severe limitations concerning accessible excited-state …
Lewis‐Pairing‐Induced Electrochemiluminescence Enhancement from Electron Donor‐Acceptor Diads Decorated with Tris (pentafluorophenyl) borane as an …
T Ikeda, K Tahara, R Ishimatsu, T Ono… - Angewandte Chemie …, 2023 - Wiley Online Library
This study reports an effective peripheral decoration of organic donor‐acceptor diads with B
(C6F5) 3 for stabilizing electrogenerated radical ions. By employing a common p‐type …
(C6F5) 3 for stabilizing electrogenerated radical ions. By employing a common p‐type …
Borylation in the Second Coordination Sphere of FeII Cyanido Complexes and Its Impact on Their Electronic Structures and Excited-State Dynamics
L Schmid, P Chábera, I Rüter, A Prescimone… - Inorganic …, 2022 - ACS Publications
Second coordination sphere interactions of cyanido complexes with hydrogen-bonding
solvents and Lewis acids are known to influence their electronic structures, whereby the non …
solvents and Lewis acids are known to influence their electronic structures, whereby the non …
Bis-cyclometalated iridium complexes with chelating dicarbene ancillary ligands
In this work, we report that covalent postsynthetic modification can be used for the
preparation of a class of bis-cyclometalated iridium complexes featuring Chugaev-type …
preparation of a class of bis-cyclometalated iridium complexes featuring Chugaev-type …
Combined Nucleophilic and Electrophilic Functionalization to Optimize Blue Phosphorescence in Cyclometalated Platinum Complexes
Ligand-based functionalization strategies have emerged as powerful approaches to tune
and optimize blue phosphorescence, which can involve nucleophilic addition to coordinated …
and optimize blue phosphorescence, which can involve nucleophilic addition to coordinated …