Operando scanning electrochemical probe microscopy during electrocatalysis

C Santana Santos, BN Jaato, I Sanjuán… - Chemical …, 2023 - ACS Publications
Scanning electrochemical probe microscopy (SEPM) techniques can disclose the local
electrochemical reactivity of interfaces in single-entity and sub-entity studies. Operando …

Mechanically controllable break junctions for molecular electronics

D **ang, H Jeong, T Lee, D Mayer - Advanced Materials, 2013 - Wiley Online Library
A mechanically controllable break junction (MCBJ) represents a fundamental technique for
the investigation of molecular electronic junctions, especially for the study of the electronic …

Orthogonally modulated molecular transport junctions for resettable electronic logic gates

F Meng, YM Hervault, Q Shao, B Hu, L Norel… - Nature …, 2014 - nature.com
Individual molecules have been demonstrated to exhibit promising applications as
functional components in the fabrication of computing nanocircuits. Based on their …

A single-molecule blueprint for synthesis

I Stone, RL Starr, Y Zang, C Nuckolls… - Nature Reviews …, 2021 - nature.com
Chemical reactions that occur at nanostructured electrodes have garnered widespread
interest because of their potential applications in fields including nanotechnology, green …

Nonlinear charge transport in redox molecular junctions: A Marcus perspective

A Migliore, A Nitzan - Acs Nano, 2011 - ACS Publications
Redox molecular junctions are molecular conduction junctions that involve more than one
oxidation state of the molecular bridge. This property is derived from the ability of the …

Do molecular conductances correlate with electrochemical rate constants? Experimental insights

XS Zhou, L Liu, P Fortgang, AS Lefevre… - Journal of the …, 2011 - ACS Publications
We measured single-molecule conductances for three different redox systems self-
assembled onto gold by the STMBJ method and compared them with electrochemical …

Single‐Molecule Sensing of Environmental pH—an STM Break Junction and NEGF‐DFT Approach

Z Li, M Smeu, S Afsari, Y **ng… - Angewandte Chemie …, 2014 - Wiley Online Library
Sensors play a significant role in the detection of toxic species and explosives, and in the
remote control of chemical processes. In this work, we report a single‐molecule‐based pH …

Regulating a benzodifuran single molecule redox switch via electrochemical gating and optimization of molecule/electrode coupling

Z Li, H Li, S Chen, T Froehlich, C Yi… - Journal of the …, 2014 - ACS Publications
We report a novel strategy for the regulation of charge transport through single molecule
junctions via the combination of external stimuli of electrode potential, internal modulation of …

Single-Molecule Observation of Redox Reactions Enabled by Rigid and Isolated Tripodal Molecules

Y Kobayashi, Y Yokota, RA Wong, M Hong… - The Journal of …, 2022 - ACS Publications
Tracking various chemical reactions, including electrochemical and photochemical reactions
at the single-molecule level, is expected to yield a great deal of knowledge from both …

Irreversibility and hysteresis in redox molecular conduction junctions

A Migliore, A Nitzan - Journal of the American Chemical Society, 2013 - ACS Publications
In this work we present and discuss theoretical models of redox molecular junctions that
account for recent observations of nonlinear charge transport phenomena, such as …