Operando scanning electrochemical probe microscopy during electrocatalysis
Scanning electrochemical probe microscopy (SEPM) techniques can disclose the local
electrochemical reactivity of interfaces in single-entity and sub-entity studies. Operando …
electrochemical reactivity of interfaces in single-entity and sub-entity studies. Operando …
Mechanically controllable break junctions for molecular electronics
A mechanically controllable break junction (MCBJ) represents a fundamental technique for
the investigation of molecular electronic junctions, especially for the study of the electronic …
the investigation of molecular electronic junctions, especially for the study of the electronic …
Orthogonally modulated molecular transport junctions for resettable electronic logic gates
Individual molecules have been demonstrated to exhibit promising applications as
functional components in the fabrication of computing nanocircuits. Based on their …
functional components in the fabrication of computing nanocircuits. Based on their …
A single-molecule blueprint for synthesis
Chemical reactions that occur at nanostructured electrodes have garnered widespread
interest because of their potential applications in fields including nanotechnology, green …
interest because of their potential applications in fields including nanotechnology, green …
Nonlinear charge transport in redox molecular junctions: A Marcus perspective
Redox molecular junctions are molecular conduction junctions that involve more than one
oxidation state of the molecular bridge. This property is derived from the ability of the …
oxidation state of the molecular bridge. This property is derived from the ability of the …
Do molecular conductances correlate with electrochemical rate constants? Experimental insights
XS Zhou, L Liu, P Fortgang, AS Lefevre… - Journal of the …, 2011 - ACS Publications
We measured single-molecule conductances for three different redox systems self-
assembled onto gold by the STMBJ method and compared them with electrochemical …
assembled onto gold by the STMBJ method and compared them with electrochemical …
Single‐Molecule Sensing of Environmental pH—an STM Break Junction and NEGF‐DFT Approach
Sensors play a significant role in the detection of toxic species and explosives, and in the
remote control of chemical processes. In this work, we report a single‐molecule‐based pH …
remote control of chemical processes. In this work, we report a single‐molecule‐based pH …
Regulating a benzodifuran single molecule redox switch via electrochemical gating and optimization of molecule/electrode coupling
We report a novel strategy for the regulation of charge transport through single molecule
junctions via the combination of external stimuli of electrode potential, internal modulation of …
junctions via the combination of external stimuli of electrode potential, internal modulation of …
Single-Molecule Observation of Redox Reactions Enabled by Rigid and Isolated Tripodal Molecules
Y Kobayashi, Y Yokota, RA Wong, M Hong… - The Journal of …, 2022 - ACS Publications
Tracking various chemical reactions, including electrochemical and photochemical reactions
at the single-molecule level, is expected to yield a great deal of knowledge from both …
at the single-molecule level, is expected to yield a great deal of knowledge from both …
Irreversibility and hysteresis in redox molecular conduction junctions
In this work we present and discuss theoretical models of redox molecular junctions that
account for recent observations of nonlinear charge transport phenomena, such as …
account for recent observations of nonlinear charge transport phenomena, such as …