Solid state 17O NMR—an introduction to the background principles and applications to inorganic materials

SE Ashbrook, ME Smith - Chemical Society Reviews, 2006 - pubs.rsc.org
Oxygen is a key chemical element and solid state NMR can provide unique insight into the
its local environment. In the last decade there have been significant advances (sensitivity …

[HTML][HTML] A comprehensive review of synthesis, characterization, and applications of aluminosilicate materials-based geopolymers

M El Alouani, H Saufi, B Aouan, R Bassam… - Environmental …, 2024 - Elsevier
The increase in the cement industry's production, especially the production of Ordinary
Portland Cement (OPC), increases the amount of CO 2 released into the atmosphere, one of …

29Si NMR Study of Structural Ordering in Aluminosilicate Geopolymer Gels

P Duxson, JL Provis, GC Lukey, F Separovic… - Langmuir, 2005 - ACS Publications
A systematic series of aluminosilicate geopolymer gels was synthesized and then analyzed
using 29Si magic-angle spinning nuclear magnetic resonance (MAS NMR) in combination …

17O Labeling Reveals Paired Active Sites in Zeolite Catalysts

K Chen, A Zornes, V Nguyen, B Wang… - Journal of the …, 2022 - ACS Publications
Current needs for extending zeolite catalysts beyond traditional gas-phase hydrocarbon
chemistry demand detailed characterization of active site structures, distributions, and …

Al–O–Al and Si–O–Si sites in framework aluminosilicate glasses with Si/Al= 1: quantification of framework disorder

SK Lee, JF Stebbins - Journal of Non-Crystalline Solids, 2000 - Elsevier
We present for the first time, direct and clear experimental evidence of Al–O–Al and Si–O–Si
linkages in charge-balanced aluminosilicate glasses with Si/Al= 1, such as NaAlSiO4 …

The Structure of Aluminosilicate Glasses:  High-Resolution 17O and 27Al MAS and 3QMAS NMR Study

SK Lee, JF Stebbins - The Journal of Physical Chemistry B, 2000 - ACS Publications
We investigate short-range order and local atomic configuration in charge-balanced
aluminosilicate glasses as functions of composition, using 17O and 27Al MAS and triple …

[KNIHA][B] Porous materials

DW Bruce, D O'Hare, RI Walton - 2011 - books.google.com
In the past few decades, the increasingly routine use of advanced structural probes for
studying the structure and dynamics of the solid state has led to some dramatic …

Exploiting NMR spectroscopy for the study of disorder in solids

RF Moran, DM Dawson… - International Reviews in …, 2017 - Taylor & Francis
Although the solid state is typically characterised by inherent periodicity, many interesting
physical and chemical properties of solids arise from a variation in this, ie changes in the …

Statistical thermodynamic model for Si/Al ordering in amorphous aluminosilicates

JL Provis, P Duxson, GC Lukey… - Chemistry of …, 2005 - ACS Publications
A statistical thermodynamic model for the ordering of aluminum-and silicon-centered
tetrahedra in fully condensed X-ray amorphous aluminosilicate network structures is …

Elucidation of the Al/Si Ordering in Gehlenite Ca2Al2SiO7 by Combined 29Si and 27Al NMR Spectroscopy/Quantum Chemical Calculations

P Florian, E Veron, TFG Green, JR Yates… - Chemistry of …, 2012 - ACS Publications
We have investigated the Al/Si ordering in the pseudoisolated pairs of tetrahedral sites of the
structure of crystalline gehlenite Ca2Al2SiO7 by means of 29Si and 27Al NMR and first …