Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

Structure and nanostructure in ionic liquids

R Hayes, GG Warr, R Atkin - Chemical reviews, 2015 - ACS Publications
Much of chemistry is concerned with the study of reactions and processes in solution, that is,
where liquids are used as solvents. 2, 3 The solvent is the (excess) liquid phase in which …

Ionic liquids at electrified interfaces

MV Fedorov, AA Kornyshev - Chemical reviews, 2014 - ACS Publications
Until recently,“room-temperature”(< 100− 150 C) liquidstate electrochemistry was mostly
electrochemistry of diluted electrolytes 1− 4 where dissolved salt ions were surrounded by a …

Effect of alkyl chain length and anion species on the interfacial nanostructure of ionic liquids at the Au (111)–ionic liquid interface as a function of potential

H Li, F Endres, R Atkin - Physical Chemistry Chemical Physics, 2013 - pubs.rsc.org
Colloid probe atomic force microscopy (AFM) force measurements are used to elucidate the
effect of variation in the cation alkyl chain length and the anion species on IL nanostructure …

Potential‐Dependent Adlayer Structure and Dynamics at the Ionic Liquid/Au (111) Interface: A Molecular‐Scale In Situ Video‐STM Study

R Wen, B Rahn, OM Magnussen - … Chemie International Edition, 2015 - Wiley Online Library
Room‐temperature ionic liquids are of great current interest for electrochemical applications
in material and energy science. Essential for understanding the electrochemical reactivity of …

Structure and dynamics of the interfacial layer between ionic liquids and electrode materials

R Atkin, N Borisenko, M Drüschler, F Endres… - Journal of Molecular …, 2014 - Elsevier
In this overview paper we present a combined in situ STM, AFM and EIS study on the
structure and dynamics of the interfacial layers between Au (111) and two extremely pure …

Specific heat control of nanofluids: A critical review

H Riazi, T Murphy, GB Webber, R Atkin… - International Journal of …, 2016 - Elsevier
Specific heat is a key thermal property in energy systems and is directly linked with heat
storage and transfer. Concentrated solar thermal (CST) power plants which incorporate …

Electrical double layer in ionic liquids: Structural transitions from multilayer to monolayer structure at the interface

K Kirchner, T Kirchner, V Ivaništšev, MV Fedorov - Electrochimica Acta, 2013 - Elsevier
We have studied structural transitions in the electrical double layer of ionic liquids by
molecular dynamics simulations. A model coarse grained room temperature ionic liquid …

Ionic liquid–metal interface: The origins of capacitance peaks

IV Voroshylova, H Ers, V Koverga… - Electrochimica …, 2021 - Elsevier
The complex nature of electrode charge screening is well-known for ionic liquids (ILs). Due
to strong ion–ion correlations, these electrolytes form a distinctive layered structure at …

In situ PM-IRRAS of a glassy carbon electrode/deep eutectic solvent interface

L Vieira, R Schennach, B Gollas - Physical Chemistry Chemical …, 2015 - pubs.rsc.org
The interface of a 1: 2 molar choline chloride/ethylene glycol deep eutectic solvent with a
glassy carbon electrode has been investigated by polarization modulation reflection …