Engineering inorganic interfaces using molecular nanolayers
Advances in interface science over the last 20 years have demonstrated the use of
molecular nanolayers (MNLs) at inorganic interfaces to access emergent phenomena and …
molecular nanolayers (MNLs) at inorganic interfaces to access emergent phenomena and …
Optical manipulation of work function contrasts on metal thin films
Work function is a crucial metric in every optoelectronic device to ensure a specific charge
transport scheme. However, the number of stable conductive materials available in a given …
transport scheme. However, the number of stable conductive materials available in a given …
Nanomolecularly-induced Effects at Titania/Organo-Diphosphonate Interfaces for Stable Hybrid Multilayers with Emergent Properties
Nanoscale hybrid inorganic–organic multilayers are attractive for accessing emergent
phenomena and properties through superposition of nanomolecularly-induced interface …
phenomena and properties through superposition of nanomolecularly-induced interface …
Selective Pd recovery from acidic leachates by 3-mercaptopropylphosphonic acid grafted TiO 2: does surface coverage correlate to performance?
Modification of metal oxides with organophosphonic acids (PAs) provides the ability to
control and tailor the surface properties. The metal oxide phosphonic acid bond (M–O–P) is …
control and tailor the surface properties. The metal oxide phosphonic acid bond (M–O–P) is …
Tailoring electrical transport across metal–thermoelectric interfaces using a nanomolecular monolayer
We report a 13-fold increase in electrical contact conductivity Σ c upon introducing a 1, 8-
octanedithiol (ODT) monolayer at Cu–Bi2Te3 interfaces. In contrast introducing ODT at Ni …
octanedithiol (ODT) monolayer at Cu–Bi2Te3 interfaces. In contrast introducing ODT at Ni …
Frequency-tunable toughening in a polymer-metal-ceramic stack using an interfacial molecular nanolayer
Interfacial toughening in composite materials is reasonably well understood for static
loading, but little is known for cyclic loading. Here, we demonstrate that introducing an …
loading, but little is known for cyclic loading. Here, we demonstrate that introducing an …
Spray coating vs. immersion for self-assembly of gemini perfluorinated phosphonic acids on indium tin oxide
GAL Andreatta, N Blondiaux, J Gay, S Unterhofer… - Thin Solid Films, 2021 - Elsevier
Self-assembled monolayers (SAMs) are widely used to engineer the surface properties of
metals and metal oxide layers. This article reports the fabrication of gemini perfluorinated …
metals and metal oxide layers. This article reports the fabrication of gemini perfluorinated …
[HTML][HTML] Work function tuning at Au-HfO2 interfaces using organophosphonate monolayers
We show that introducing organophosphonate nanomolecular monolayers (NMLs) at Au-
HfO 2 interfaces shift the effective work function by 0.2 eV≥ ΔΦ eff≥− 0.6 eV, due to NML …
HfO 2 interfaces shift the effective work function by 0.2 eV≥ ΔΦ eff≥− 0.6 eV, due to NML …
[HTML][HTML] Tailoring Al-SiO2 interfacial work function using an organophosphonate nanolayer
We show that introducing a mercaptan-terminated organophosphonate nanomolecular layer
(NML) at the Al-SiO 2 interface decreases the effective metal work function Φ eff by 0.67 eV …
(NML) at the Al-SiO 2 interface decreases the effective metal work function Φ eff by 0.67 eV …
[HTML][HTML] Molecular length effect on work function shifts at copper-organophosphonate-hafnia interfaces
We demonstrate that inserting a mercaptan-terminated organophosphonic acid monolayer
at a Cu-HfO 2 interface can alter the metal work function by− 0.1 eV≤ ΔΦ≤− 0.4 eV. The …
at a Cu-HfO 2 interface can alter the metal work function by− 0.1 eV≤ ΔΦ≤− 0.4 eV. The …