Manipulation of molecules with electromagnetic fields

M Lemeshko, RV Krems, JM Doyle, S Kais - Molecular Physics, 2013 - Taylor & Francis
The goal of the present article is to review the major developments that have led to the
current understanding of molecule–field interactions and experimental methods for …

Polaritonic chemistry with organic molecules

J Feist, J Galego, FJ Garcia-Vidal - ACS Photonics, 2018 - ACS Publications
We present an overview of the general concepts of polaritonic chemistry with organic
molecules, ie, the manipulation of chemical structure that can be achieved through strong …

Structure and dynamics of electronically excited molecular systems

S Mahapatra - Wiley Interdisciplinary Reviews: Computational …, 2022 - Wiley Online Library
Abstract Structure and dynamics of electronic excited states of molecular systems is of
contemporary interest to understand a rich variety of processes ranging from molecular …

Direct signature of light-induced conical intersections in diatomics

GJ Halász, Á Vibók, LS Cederbaum - The Journal of Physical …, 2015 - ACS Publications
Nonadiabatic effects are ubiquitous in physics, chemistry, and biology. They are strongly
amplified by conical intersections (CIs), which are degeneracies between electronic states of …

Born–Oppenheimer approximation in optical cavities: from success to breakdown

C Fábri, GJ Halász, LS Cederbaum, Á Vibók - Chemical Science, 2021 - pubs.rsc.org
The coupling of a molecule and a cavity induces nonadiabaticity in the molecule which
makes the description of its dynamics complicated. For polyatomic molecules, reduced …

Control of nuclear dynamics through conical intersections and electronic coherences

C Arnold, O Vendrell, R Welsch, R Santra - Physical review letters, 2018 - APS
The effect of nuclear dynamics and conical intersections on electronic coherences is
investigated employing a two-state, two-mode linear vibronic coupling model. Exact …

Observation of quantum interferences via light-induced conical intersections in diatomic molecules

A Natan, MR Ware, VS Prabhudesai, U Lev… - Physical Review Letters, 2016 - APS
We observe energy-dependent angle-resolved diffraction patterns in protons from strong-
field dissociation of the molecular hydrogen ion H 2+. The interference is a characteristic of …

Control of 1, 3-cyclohexadiene photoisomerization using light-induced conical intersections

J Kim, H Tao, JL White, VS Petrovic… - The Journal of …, 2012 - ACS Publications
We have studied the photoinduced isomerization from 1, 3-cyclohexadiene to 1, 3, 5-
hexatriene in the presence of an intense ultrafast laser pulse. We find that the laser field …

Polariton induced conical intersection and berry phase

MH Farag, A Mandal, P Huo - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
We investigate the Polariton induced conical intersection (PICI) created from coupling a
diatomic molecule with the quantized photon mode inside an optical cavity, and the …

Ultrafast dynamics in the vicinity of quantum light-induced conical intersections

A Csehi, M Kowalewski, GJ Halász… - New Journal of …, 2019 - iopscience.iop.org
Nonadiabatic effects appear due to avoided crossings or conical intersections (CIs) that are
either intrinsic properties in field-free space or induced by a classical laser field in a …