Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

Single-atom alloy catalysis

RT Hannagan, G Giannakakis… - Chemical …, 2020 - ACS Publications
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …

A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation

AR Poerwoprajitno, L Gloag, J Watt, S Cheong, X Tan… - Nature Catalysis, 2022 - nature.com
Single Pt atom catalysts are key targets because a high exposure of Pt substantially
enhances electrocatalytic activity. In addition, PtRu alloy nanoparticles are the most active …

First-principles design of a single-atom–alloy propane dehydrogenation catalyst

RT Hannagan, G Giannakakis, R Réocreux… - Science, 2021 - science.org
The complexity of heterogeneous catalysts means that a priori design of new catalytic
materials is difficult, but the well-defined nature of single-atom–alloy catalysts has made it …

Electronic modulation with Pt-incorporated NiFe layered double hydroxide for ultrastable overall water splitting at 1000 mA cm− 2

X He, X Han, X Zhou, J Chen, J Wang, Y Chen… - Applied Catalysis B …, 2023 - Elsevier
Achieving large current density is crucial to the practical application of large-scale hydrogen
production by water splitting, but it is hindered by sluggish and unstable catalysts. Herein, a …

Noble-metal based random alloy and intermetallic nanocrystals: syntheses and applications

M Zhou, C Li, J Fang - Chemical Reviews, 2020 - ACS Publications
Precise control over the size, shape, composition, structure, and crystal phase of random
alloy and intermetallic nanocrystals has been intensively explored in technologically …

Engineering the electronic structure of single atom Ru sites via compressive strain boosts acidic water oxidation electrocatalysis

Y Yao - Controllable Synthesis and Atomic Scale Regulation of …, 2022 - Springer
Single-atom precious metal catalysts hold the promise of perfect atom utilization, yet control
of their activity and stability remains challenging. Here we show that engineering the …

High-entropy alloys as a discovery platform for electrocatalysis

TAA Batchelor, JK Pedersen, SH Winther, IE Castelli… - Joule, 2019 - cell.com
High-entropy alloys (HEAs) provide a near-continuous distribution of adsorption energies.
With a minority of sites having optimal properties that dominate the catalysis, the overall …

Transition‐metal‐doped RuIr bifunctional nanocrystals for overall water splitting in acidic environments

J Shan, T Ling, K Davey, Y Zheng… - Advanced Materials, 2019 - Wiley Online Library
The establishment of electrocatalysts with bifunctionality for efficient oxygen evolution
reaction (OER) and hydrogen evolution reaction (HER) in acidic environments is necessary …

Atomically dispersed iron hydroxide anchored on Pt for preferential oxidation of CO in H2

L Cao, W Liu, Q Luo, R Yin, B Wang, J Weissenrieder… - Nature, 2019 - nature.com
Proton-exchange-membrane fuel cells (PEMFCs) are attractive next-generation power
sources for use in vehicles and other applications, with development efforts focusing on …