Carbon–hydrogen bond functionalizations provide an attractive method for streamlining
organic synthesis, and many strategies have been developed for conducting these …

Converting any desired C− H bond to the intended C− Z bond in a given organic molecule
could be the final peak of the C− H functionalization methodology. Among the three types of …

C–H/N–H cross-coupling has become a key technology for the selective conjugation of
azole drug molecules. However, the development of new synthetic models and green …

Starting from nitroarenes, under hydrosilylation conditions, using a well‐defined N‐
heterocyclic carbene iron (0) catalyst,(IMes) Fe (CO) 4, the corresponding aniline derivatives …

Triazolinediones are known as highly reactive dienophiles that can also act as electrophilic
amination reagents towards enolisable C–H bonds (ionic pathway) or weak C–H bonds …

The functionalization of C–H bonds has become a major thread of research in organic
synthesis that can be assessed from different angles, for instance depending on the type of …

Iron catalyzed coupling of β-amino alcohols with allylic alcohols for the synthesis of 3, 4-
dihydro-2H-pyrrole derivatives has been developed. Mechanistic studies suggest that the …

A catalytic asymmetric conjugate addition/Schmidt-type rearrangement of vinyl azides and
(E)-alkenyloxindoles was realized. It afforded a variety of optically active 3, 2′-pyrrolinyl …

Herein, a versatile highly regioselective three-component annulation of simple aromatic
ketones and methylamines using a hypervalent iodine reagent for polyarylated 1-pyrrolines …

The synthesis of 1-pyrrolines from cyclobutanol derivatives and an aminating reagent
(MsONH3OTf) has been developed. This one-pot procedure achieves C–N bond/C═ N …