Metal‐Organic Frameworks for Photocatalytic Water Splitting and CO2 Reduction

K Sun, Y Qian, HL Jiang - Angewandte Chemie, 2023 - Wiley Online Library
Photocatalytic water splitting and carbon dioxide (CO2) reduction provide promising
solutions to global energy and environmental issues. In recent years, metal‐organic …

Carbon nitride based materials: more than just a support for single-atom catalysis

GFSR Rocha, MAR da Silva, A Rogolino… - Chemical Society …, 2023 - pubs.rsc.org
Recently, the missing link between homogeneous and heterogeneous catalysis has been
found and it was named single-atom catalysis (SAC). However, the SAC field still faces …

Engineering Single-Atom Active Sites on Covalent Organic Frameworks for Boosting CO2 Photoreduction

L Ran, Z Li, B Ran, J Cao, Y Zhao, T Shao… - Journal of the …, 2022 - ACS Publications
Solar carbon dioxide (CO2) conversion is an emerging solution to meet the challenges of
sustainable energy systems and environmental/climate concerns. However, the construction …

Photocatalytic CO2 reduction using La-Ni bimetallic sites within a covalent organic framework

M Zhou, Z Wang, A Mei, Z Yang, W Chen, S Ou… - Nature …, 2023 - nature.com
The precise construction of photocatalysts with diatomic sites that simultaneously foster light
absorption and catalytic activity is a formidable challenge, as both processes follow distinct …

Linker Engineering of Sandwich‐Structured Metal–Organic Framework Composites for Optimized Photocatalytic H2 Production

S Wang, Z Ai, X Niu, W Yang, R Kang, Z Lin… - Advanced …, 2023 - Wiley Online Library
While the microenvironment around catalytic sites is recognized to be crucial in
thermocatalysis, its roles in photocatalysis remain subtle. In this work, a series of sandwich …

Challenges and opportunities in engineering the electronic structure of single-atom catalysts

V Giulimondi, S Mitchell, J Pérez-Ramírez - ACS catalysis, 2023 - ACS Publications
Controlling the electronic structure of transition-metal single-atom heterogeneous catalysts
(SACs) is crucial to unlocking their full potential. The ability to do this with increasing …

Dislocated Bilayer MOF Enables High‐Selectivity Photocatalytic Reduction of CO2 to CO

J Liang, H Yu, J Shi, B Li, L Wu, M Wang - Advanced materials, 2023 - Wiley Online Library
The highly selective photoreduction of CO2 into valuable small‐molecule chemical
feedstocks such as CO is an effective strategy for addressing the energy crisis and …

Metal organic framework-based antibacterial agents and their underlying mechanisms

D Han, X Liu, S Wu - Chemical Society Reviews, 2022 - pubs.rsc.org
Bacteria, as the most abundant living organisms, have always been a threat to human life
until the development of antibiotics. However, with the wide use of antibiotics over a long …

Tandem Photocatalysis of CO2 to C2H4 via a Synergistic Rhenium-(I) Bipyridine/Copper-Porphyrinic Triazine Framework

R Xu, DH Si, SS Zhao, QJ Wu, XS Wang… - Journal of the …, 2023 - ACS Publications
The photocatalytic conversion of CO2 into C2+ products such as ethylene is a promising
path toward the carbon neutral goal but remains a big challenge due to the high activation …

Surface modification of 2D photocatalysts for solar energy conversion

C Feng, ZP Wu, KW Huang, J Ye… - Advanced Materials, 2022 - Wiley Online Library
Abstract 2D materials show many particular properties, such as high surface‐to‐volume
ratio, high anisotropic degree, and adjustable chemical functionality. These unique …