Recent progress in the science of complex coacervation

CE Sing, SL Perry - Soft Matter, 2020 - pubs.rsc.org
Complex coacervation is an associative, liquid–liquid phase separation that can occur in
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …

50th Anniversary Perspective: A Perspective on Polyelectrolyte Solutions

M Muthukumar - Macromolecules, 2017 - ACS Publications
From the beginning of life with the information-containing polymers until the present era of a
plethora of water-based materials in health care industry and biotechnology, polyelectrolytes …

Polyelectrolyte complex coacervates: Recent developments and new frontiers

AM Rumyantsev, NE Jackson… - Annual Review of …, 2021 - annualreviews.org
Polyelectrolyte complex coacervates represent a wide class of materials with applications
ranging from coatings and adhesives to pharmaceutical technologies. They also underpin …

Complex coacervate‐based materials for biomedicine

WC Blocher, SL Perry - Wiley Interdisciplinary Reviews …, 2017 - Wiley Online Library
There has been increasing interest in complex coacervates for deriving and transporting
biomaterials. Complex coacervates are a dense, polyelectrolyte‐rich liquid that results from …

Chirality-selected phase behaviour in ionic polypeptide complexes

SL Perry, L Leon, KQ Hoffmann, MJ Kade… - Nature …, 2015 - nature.com
Polyelectrolyte complexes present new opportunities for self-assembled soft matter. Factors
determining whether the phase of the complex is solid or liquid remain unclear. Ionic …

The effect of salt on the complex coacervation of vinyl polyelectrolytes

SL Perry, Y Li, D Priftis, L Leon, M Tirrell - Polymers, 2014 - mdpi.com
Complex coacervation is an electrostatically-driven phase separation phenomenon that is
utilized in a wide range of everyday applications and is of great interest for the creation of …

Structure and rheology of polyelectrolyte complex coacervates

AB Marciel, S Srivastava, MV Tirrell - Soft Matter, 2018 - pubs.rsc.org
Scattering investigations of the structure and chain conformations, and the rheological
properties of polyelectrolyte complexes (PECs) comprising model polyelectrolytes are …

Designing electrostatic interactions via polyelectrolyte monomer sequence

TK Lytle, LW Chang, N Markiewicz, SL Perry… - ACS central …, 2019 - ACS Publications
Charged polymers are ubiquitous in biological systems because electrostatic interactions
can drive complicated structure formation and respond to environmental parameters such as …

Role of associative charging in the entropy–energy balance of polyelectrolyte complexes

VS Rathee, H Sidky, BJ Sikora… - Journal of the American …, 2018 - ACS Publications
Polyelectrolytes may be classified into two primary categories (strong and weak) depending
on how their charge state responds to the local environment. Both of these find use in many …

Rheological characterization of liquid-to-solid transitions in bulk polyelectrolyte complexes

Y Liu, B Momani, HH Winter, SL Perry - Soft Matter, 2017 - pubs.rsc.org
Polyelectrolyte complexation has long been known to result in both liquid and solid
complexes. However, the exact nature of the liquid-to-solid transition remains an open …