Bio-inspired mononuclear nonheme metal peroxo complexes: Synthesis, structures and mechanistic studies toward understanding enzymatic reactions
Metalloenzymes utilize inexpensive and earth-abundant transition metal ions as important
co-factors to enable binding of a dioxygen molecule so that it can be used in various …
co-factors to enable binding of a dioxygen molecule so that it can be used in various …
Metal ion-coupled electron-transfer reactions of metal-oxygen complexes
Redox-inactive and-active metal ions that act as Lewis acids are essential cofactors in
modulating the redox reactivity of metal–oxygen complexes and metalloenzymes, such as …
modulating the redox reactivity of metal–oxygen complexes and metalloenzymes, such as …
Synthetic access to a framework-stabilized and fully sulfided analogue of an Anderson polyoxometalate that is catalytically competent for reduction reactions
Polyoxometalates (POMs) featuring 7, 12, 18, or more redox-accessible transition metal ions
are ubiquitous as selective catalysts, especially for oxidation reactions. The corresponding …
are ubiquitous as selective catalysts, especially for oxidation reactions. The corresponding …
Bimolecular reactivity of 3d metal-centered excited states (Cr, Mn, Fe, Co)
C Förster, K Heinze - Chemical Physics Reviews, 2022 - pubs.aip.org
Metal-centered (MC) excited states (ESs) of 3d transition metal complexes (TMCs) often
possess rather low energies so that these represent the lowest energy ESs. Additionally, MC …
possess rather low energies so that these represent the lowest energy ESs. Additionally, MC …
Oxidative Cleavage of Alkenes by O2 with a Non-Heme Manganese Catalyst
Z Huang, R Guan, M Shanmugam… - Journal of the …, 2021 - ACS Publications
The oxidative cleavage of C═ C double bonds with molecular oxygen to produce carbonyl
compounds is an important transformation in chemical and pharmaceutical synthesis. In …
compounds is an important transformation in chemical and pharmaceutical synthesis. In …
Effects of noncovalent interactions on high-spin Fe (IV)–oxido complexes
High-valent nonheme FeIV–oxido species are key intermediates in biological oxidation, and
their properties are proposed to be influenced by the unique microenvironments present in …
their properties are proposed to be influenced by the unique microenvironments present in …
Proton vs Electron: The Dual Role of Redox-Inactive Metal Ions in Permanganate Oxidation Kinetics
M Luo, H Zhang, J Guo, J Zhao, C Feng… - Environmental …, 2024 - ACS Publications
Redox-inactive metal-ion-driven modulation of the oxidation behavior of high-valent metal–
oxo complex has garnered significant interest in biological and chemical synthesis; …
oxo complex has garnered significant interest in biological and chemical synthesis; …
The effects of nonredox metal ions on the activation of peroxymonosulfate for organic pollutants degradation in aqueous solution with cobalt based catalysts: a new …
A Xu, Y Wei, Q Zou, W Zhang, Y **, Z Wang… - Journal of hazardous …, 2020 - Elsevier
Herein, a new peroxymonosulfate (PMS) activation system was proposed employing
nonredox metal ions as Lewis acids (LA), which have been widely recognized to play …
nonredox metal ions as Lewis acids (LA), which have been widely recognized to play …
Identification, Characterization, and Electronic Structures of Interconvertible Cobalt–Oxygen TAML Intermediates
The reaction of Li [(TAML) CoIII]· 3H2O (TAML= tetraamido macrocyclic tetraanionic ligand)
with iodosylbenzene at 253 K in acetone in the presence of redox-innocent metal ions (Sc …
with iodosylbenzene at 253 K in acetone in the presence of redox-innocent metal ions (Sc …
Engineered enzymes and bioinspired catalysts for energy conversion
JM Le, KL Bren - ACS Energy Letters, 2019 - ACS Publications
Metalloenzymes play critical roles in the environment by catalyzing redox reactions in
biogeochemical cycles. The elucidation of structure–function relationships in these …
biogeochemical cycles. The elucidation of structure–function relationships in these …