Porous organic polymers for electrocatalysis

DH Yang, Y Tao, X Ding, BH Han - Chemical Society Reviews, 2022 - pubs.rsc.org
Porous organic polymers (POPs) composed of organic building units linked via covalent
bonds are a class of lightweight porous network materials with high surface areas, tuneable …

Tuning Two‐Electron Oxygen‐Reduction Pathways for H2O2 Electrosynthesis via Engineering Atomically Dispersed Single Metal Site Catalysts

X Yang, Y Zeng, W Alnoush, Y Hou… - Advanced …, 2022 - Wiley Online Library
The hydrogen peroxide (H2O2) generation via the electrochemical oxygen reduction
reaction (ORR) under ambient conditions is emerging as an alternative and green strategy …

Atomically dispersed metal–nitrogen–carbon catalysts for fuel cells: advances in catalyst design, electrode performance, and durability improvement

Y He, S Liu, C Priest, Q Shi, G Wu - Chemical Society Reviews, 2020 - pubs.rsc.org
The urgent need to address the high-cost issue of proton-exchange membrane fuel cell
(PEMFC) technologies, particularly for transportation applications, drives the development of …

Corroles at work: A small macrocycle for great applications

C Di Natale, CP Gros, R Paolesse - Chemical Society Reviews, 2022 - pubs.rsc.org
Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …

Enzyme‐inspired iron porphyrins for improved electrocatalytic oxygen reduction and evolution reactions

L **e, XP Zhang, B Zhao, P Li, J Qi, X Guo… - Angewandte …, 2021 - Wiley Online Library
Nature uses Fe porphyrin sites for the oxygen reduction reaction (ORR). Synthetic Fe
porphyrins have been extensively studied as ORR catalysts, but activity improvement is …

Metal‐corrole‐based porous organic polymers for electrocatalytic oxygen reduction and evolution reactions

H Lei, Q Zhang, Z Liang, H Guo, Y Wang… - Angewandte …, 2022 - Wiley Online Library
Integrating molecular catalysts into designed frameworks often enables improved catalysis.
Compared with porphyrin‐based frameworks, metal‐corrole‐based frameworks have been …

Recent developments of microenvironment engineering of single‐atom catalysts for oxygen reduction toward desired activity and selectivity

L Li, B Huang, X Tang, Y Hong, W Zhai… - Advanced Functional …, 2021 - Wiley Online Library
Oxygen reduction reaction (ORR) is an essential process for sustainable energy supply and
sufficient chemical production in modern society. Single‐atom catalysts (SACs) exhibit great …

Adapting Synthetic Models of Heme/Cu Sites to Energy‐Efficient Electrocatalytic Oxygen Reduction Reaction

J Meng, H Qin, H Lei, X Li, J Fan… - Angewandte Chemie …, 2023 - Wiley Online Library
In nature, cytochrome c oxidases catalyze the 4e− oxygen reduction reaction (ORR) at the
heme/Cu site, in which CuI is used to assist O2 activation. Because of the thermodynamic …

Engineering organic polymers as emerging sustainable materials for powerful electrocatalysts

X Cui, M Wu, X Liu, B He, Y Zhu, Y Jiang… - Chemical Society …, 2024 - pubs.rsc.org
Cost-effective and high-efficiency catalysts play a central role in various sustainable
electrochemical energy conversion technologies that are being developed to generate clean …

Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two‐Electron and Four‐Electron Oxygen Reduction with Cobalt Porphyrin …

B Lv, X Li, K Guo, J Ma, Y Wang, H Lei… - Angewandte Chemie …, 2021 - Wiley Online Library
Achieving a selective 2 e− or 4 e− oxygen reduction reaction (ORR) is critical but
challenging. Herein, we report controlling ORR selectivity of Co porphyrins by tuning only …