Understanding the chiral mechanism of chiral hybrid perovskites is a prerequisite for
develo** relevant chiroptoelectronic applications. Although conventional circular …

Chiroptical responses have been an essential tool over the last decades for chemical
structural elucidation due to their exceptional sensitivity to geometry and intermolecular …

Disubstituted odd-carbon cumulenes are linear carbon wires with near-degenerate helical π-
orbitals. Such cumulenes are chiral molecules but their electronic structure consists of …

Silver nanowires (Ag NWs) present prominent waveguiding properties of subwavelength
light due to their nanoconfinement with propagating surface plasmons, which is of great …

We used second harmonic generation (SHG) spectroscopy to study the chiroptical
properties of R-, S-and racemic (RAC-) 1, 1′-bi-2-naphthol (BINOL) films with various …

Generally, the relationship between the observed circular dichroism and the enantiomeric
excess in chiral systems (CD–ee dependence) is linear. While positive nonlinear behavior …

Several theoretical studies have proposed strategies to generate helical molecular orbitals
(Hel‐MOs) in [n] cumulenes and oligoynes. While chiral even‐[n] cumulenes feature Hel …

Helical frontier molecular orbitals (MOs) appear in disubstituted allenes and even-n
cumulenes. Chiral molecules are optically active, but while these molecules are single …

Three new spirobifluorene iridaaromatic compounds bearing electron-withdrawing or
electron-donor substituents or another iridanaphthalene moiety have been synthesized and …

Chiroptical responses are valuable for the structural determination of dissymmetric
molecules. However, the development of everyday applications based on chiroptical …