The chemistry of metal organic framework materials

SE Skrabalak, R Vaidhyanathan - Chemistry of Materials, 2023 - ACS Publications
The journal started its 35th year by celebrating 35 recent manuscripts in a virtual issue that
highlighted diverse materialsbased research: battery materials, MXenes and layered …

The Effect of pendent groups upon flexibility in coordination networks with square lattice topology

X Li, D Sensharma, K Koupepidou, XJ Kong… - ACS Materials …, 2023 - ACS Publications
Gas or vapor-induced phase transformations in flexible coordination networks (CNs) offer
the potential to exceed the performance of their rigid counterparts for separation and storage …

Water vapour and gas induced phase transformations in an 8-fold interpenetrated diamondoid metal–organic framework

A Subanbekova, VI Nikolayenko… - Journal of Materials …, 2023 - pubs.rsc.org
In this work, we report the synthesis, structural characterisation and sorption properties of an
8-fold interpenetrated diamondoid (dia) metal–organic framework (MOF) that is sustained by …

Water vapour induced structural flexibility in a square lattice coordination network

K Koupepidou, AA Bezrukov, DC Castell… - Chemical …, 2023 - pubs.rsc.org
Herein, we introduce a new square lattice topology coordination network, sql-(1, 3-bib)(ndc)-
Ni, with three types of connection and detail its gas and vapour induced phase …

Reversible Phase Transformations in a Double-Walled Diamondoid Coordination Network with a Stepped Isotherm for Methane

X Li, D Sensharma, L Loots, S Geng… - Journal of the …, 2024 - ACS Publications
Flexible metal–organic materials (FMOMs) with stepped isotherms can offer enhanced
working capacity in storage applications such as adsorbed natural gas (ANG) storage …

Modulation of Water Vapor Sorption by Pore Engineering in Isostructural Square Lattice Topology Coordination Networks

X Li, AA Bezrukov, W Graham… - … Applied Materials & …, 2024 - ACS Publications
We report a crystal-engineering study conducted upon a platform of three mixed-linker
square lattice (sql) coordination networks of general formula [Zn (Ria)(bphy)][bphy= 1, 2-bis …

Effect of polymorphism on the sorption properties of a flexible square-lattice topology coordination network

A Subanbekova, AA Bezrukov, V Bon… - … Applied Materials & …, 2024 - ACS Publications
The stimulus-responsive behavior of coordination networks (CNs), which switch between
closed (nonporous) and open (porous) phases, is of interest because of its potential utility in …

One Step Further: A Flexible Metal–Organic Framework that Functions as a Dual-Purpose Water Vapor Sorbent

SM Shabangu, AA Bezrukov, AC Eaby… - ACS Materials …, 2025 - ACS Publications
We report a water induced phase transformation in a flexible MOF,[Zn3 (OH) 2 (btca)
2](Hbtca= 1H-benzotriazole-5-carboxylic acid), that exhibits a two-step water vapor sorption …

Polar alcohol guest molecules regulate the stacking modes of 2-D MOF nanosheets

Y Cheng, WQ Tang, LT Geng, M Xu, JP Zhu… - Chemical …, 2024 - pubs.rsc.org
The modulation of two-dimensional metal–organic framework (2-D MOF) nanosheet
stacking is an effective means to improve the properties and promote the application of …

Rapid determination of experimental sorption isotherms from non-equilibrium sorption kinetic data

AA Bezrukov, DJ O'Hearn, V Gascón-Pérez… - Chem, 2024 - cell.com
Herein, we report a new method for rapid determination of experimental sorption isotherms
that exploits gravimetric non-equilibrium sorption kinetics data in a thin sorbent bed. In …