Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms | Chemical
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Hydrosilation reactions represent an important class of chemical transformations and there
has been considerable recent interest in expanding the scope of these reactions by …

Hydrosilanes are used as versatile coreactants in the generation of silyl-metal complexes.
Since organohydrosilanes may contain one, two, or three SiH bonds as tertiary, secondary …

Treatment of resorcinol-derived bis (phosphinite) ligands 1, 3-(R2PO) 2C6H4 (R= iPr and
Ph) with Fe (PMe3) 4 furnishes iron POCOP-pincer hydride complexes [2, 6-(R2PO) 2C6H3] …

Hydrosilylation of a variety of ketones and aldehydes using the cationic iridium catalyst
(POCOP) Ir (H)(acetone)+, 1 (POCOP= 2, 6-bis (di-tert-butylphosphinito) phenyl), is reported …

A detailed mechanistic study of the catalytic hydrosilylation of ketones with the highly active
and enantioselective iron (II) boxmi complexes as catalysts (up to> 99% ee) was carried out …

In this Perspective we discuss the ability of transition metal complexes to activate and cleave
the Si–H and B–H bonds of hydrosilanes and hydroboranes (tri-and tetra-coordinated) in an …

This work details an in-depth evaluation of an unprecedented mechanism for the
hydrosilylation of carbonyl compounds catalyzed by (PPh3) 2Re (O) 2I. The proposed …

We report the syntheses and characterization of two new sterically demanding chelate
ligands, denoted PNMe3 (N-(2-(diisopropylphosphino)-4-methylphenyl)-2, 4, 6 …

A highly active cationic Ir (III) hydride complex catalyzes the reduction of primary, secondary,
and tertiary chlorides, bromides, and iodides as well as certain fluorides by Et3SiH. The …