Dynamic weak coordination bonding of chlorocarbons enhances the catalytic performance of a metal–organic framework material
Coordination bondings have shown their critical roles in various inorganic reactions after
Alfred Werner; however, it remains challenging to find extremely weak coordination bonding …
Alfred Werner; however, it remains challenging to find extremely weak coordination bonding …
Ir-Catalyzed Selective B(3)-H Amination of o-Carboranes with NH3
Ammonia gas, NH3, is a cheap and widely used industrial feedstock, which has received
tremendous research interests in its functionalization. This work reports a breakthrough in …
tremendous research interests in its functionalization. This work reports a breakthrough in …
Steric-Effects-Directed B–H Bond Activation of para-Carboranes
PF Cui, XR Liu, ST Guo, YJ Lin… - Journal of the American …, 2021 - ACS Publications
The controllable B–H bond activation of carboranes has long been a compelling challenge.
However, as the symmetry of para-carborane places the same charge on all of its ten boron …
However, as the symmetry of para-carborane places the same charge on all of its ten boron …
Variable Metal Chelation Modes and Activation Sequence in Pd-Catalyzed B–H Poly-arylation of Carboranes
H Cao, M Chen, F Sun, Y Zhao, C Lu, X Zhang… - ACS …, 2021 - ACS Publications
The development of synthetic methods for selective multiple functionalization of B–H bonds
offers great opportunity in expanding the application potentials of carboranes. Herein …
offers great opportunity in expanding the application potentials of carboranes. Herein …
Practical Synthesis of B(9)-Halogenated Carboranes with N-Haloamides in Hexafluoroisopropanol
W Guo, C Guo, YN Ma, X Chen - Inorganic Chemistry, 2022 - ACS Publications
The B (9)-H halogenation of o-carborane and m-carborane was achieved with excellent
selectivities in hexafluoroisopropanol (HFIP) under simple reaction conditions: single …
selectivities in hexafluoroisopropanol (HFIP) under simple reaction conditions: single …
Electrochemical cage activation of carboranes
Carboranes are boron–carbon molecular clusters that possess unique properties, such as
their icosahedron geometry, high boron content, and delocalized three‐dimensional …
their icosahedron geometry, high boron content, and delocalized three‐dimensional …
Site‐Selective Functionalization of Carboranes at the Electron‐Rich Boron Vertex: Photocatalytic B− C Coupling via a Carboranyl Cage Radical
M Chen, J Xu, D Zhao, F Sun, S Tian… - Angewandte Chemie …, 2022 - Wiley Online Library
Functionalization of carboranes in a vertex‐specific manner is a perennial challenge. Here,
we report a photocatalytic B− C coupling for the selective functionalization of carboranes at …
we report a photocatalytic B− C coupling for the selective functionalization of carboranes at …