Transient absorption spectroscopy using high harmonic generation: a review of ultrafast X-ray dynamics in molecules and solids

R Geneaux, HJB Marroux… - … of the Royal …, 2019 - royalsocietypublishing.org
Attosecond science opened the door to observing nuclear and electronic dynamics in real
time and has begun to expand beyond its traditional grounds. Among several spectroscopic …

Frontiers of water oxidation: the quest for true catalysts

J Li, R Güttinger, R Moré, F Song, W Wan… - Chemical Society …, 2017 - pubs.rsc.org
Development of efficient and economic water oxidation catalysts (WOCs) remains a crucial
bottleneck on the way to artificial photosynthesis applications. Over the past few decades …

Progress in the theory of x-ray spectroscopy: From quantum chemistry to machine learning and ultrafast dynamics

CD Rankine, TJ Penfold - The Journal of Physical Chemistry A, 2021 - ACS Publications
The development of high-brilliance third-and fourth-generation light sources such as
synchrotrons and X-ray free-electron lasers (XFELs), the emergence of laboratory-based X …

Tracking the Metal-Centered Triplet in Photoinduced Spin Crossover of Fe(phen)32+ with Tabletop Femtosecond M-Edge X-ray Absorption Near-Edge Structure …

K Zhang, R Ash, GS Girolami… - Journal of the American …, 2019 - ACS Publications
Fe (II) coordination complexes are promising alternatives to Ru (II) and Ir (III) chromophores
for photoredox chemistry and solar energy conversion, but rapid deactivation of the initial …

Femtosecond soft-X-ray absorption spectroscopy of liquids with a water-window high-harmonic source

AD Smith, T Balciunas, YP Chang… - The journal of …, 2020 - ACS Publications
Femtosecond X-ray absorption spectroscopy (XAS) is a powerful method to investigate the
dynamical behavior of a system after photoabsorption in real time. So far, the application of …

Tabletop femtosecond M-edge X-ray absorption near-edge structure of FeTPPCl: Metalloporphyrin photophysics from the perspective of the metal

ES Ryland, MF Lin, MA Verkamp, K Zhang… - Journal of the …, 2018 - ACS Publications
Iron porphyrins are the active sites of many natural and artificial catalysts, and their
photoinduced dynamics have been described as either relaxation into a vibrationally hot …

X-ray Spectroscopic Interrogation of Transition-Metal-Mediated Homogeneous Catalysis: Primer and Case Studies

SN MacMillan, KM Lancaster - ACS Catalysis, 2017 - ACS Publications
In this perspective, we highlight recent studies that use X-ray spectroscopic methods to
identify and elucidate the molecular and/or electronic structures of intermediate and resting …

Extreme ultraviolet reflection–absorption spectroscopy: Probing dynamics at surfaces from a molecular perspective

S Biswas, LR Baker - Accounts of chemical research, 2022 - ACS Publications
Conspectus Extreme ultraviolet light sources based on high harmonic generation are
enabling the development of novel spectroscopic methods to help advance the frontiers of …

Accurate x-ray absorption spectra near L-and M-edges from relativistic four-component damped response time-dependent density functional theory

L Konecny, J Vicha, S Komorovsky, K Ruud… - Inorganic …, 2021 - ACS Publications
The simulation of X-ray absorption spectra requires both scalar and spin–orbit (SO)
relativistic effects to be taken into account, particularly near L-and M-edges where the SO …

Small polarons and surface defects in metal oxide photocatalysts studied using XUV reflection–absorption spectroscopy

S Bandaranayake, E Hruska, S Londo… - The Journal of …, 2020 - ACS Publications
In photocatalytic transition metal oxides, the surface electronic structure and carrier kinetics
are complicated by both charge trap** at defects and self-trap** by small polaron …