Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

C Papatriantafyllopoulou, EE Moushi… - Chemical Society …, 2016 - pubs.rsc.org
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

Relaxation dynamics of dysprosium (III) single molecule magnets

YN Guo, GF Xu, Y Guo, J Tang - Dalton Transactions, 2011 - pubs.rsc.org
Over the past decade, lanthanide compounds have become of increasing interest in the field
of Single Molecule Magnets (SMMs) due to the large inherent anisotropy of the metal ions …

Heterometallic 3d–4f single-molecule magnets

LR Piquer, EC Sañudo - Dalton Transactions, 2015 - pubs.rsc.org
The promising potential applications, such as information processing and storage or
molecular spintronics, of single-molecule magnets (SMMs) have spurred on the research of …

Co–Ln mixed-metal phosphonate grids and cages as molecular magnetic refrigerants

YZ Zheng, M Evangelisti, F Tuna… - Journal of the American …, 2012 - ACS Publications
The synthesis, structures, and magnetic properties of six families of cobalt–lanthanide mixed-
metal phosphonate complexes are reported in this Article. These six families can be divided …

Molecular metal phosphonates

J Goura, V Chandrasekhar - Chemical reviews, 2015 - ACS Publications
The carboxylate ligand,[RCO 2]−, is one of the most versatile and hence also one of the most
ubiquitous ligands in coordination chemistry.(1-4) Although fairly simple coordination modes …

Large magnetocaloric effect in a Wells-Dawson type {Ni6Gd 6P6} cage

YZ Zheng, M Evangelisti, REP Winpenny - 2011 - digital.csic.es
Magnetic refrigeration is based on the magnetocaloric effect (MCE) which relies on the
entropy change of a material when placed in a magnetic field. 1 Molecular magnets have …

Heterometallic CuII–LnIII complexes: Single molecule magnets and magnetic refrigerants

A Dey, P Bag, P Kalita, V Chandrasekhar - Coordination Chemistry …, 2021 - Elsevier
Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated
extensively for the past few years realizing the role of exchange interaction to minimize the …

Co–Gd phosphonate complexes as magnetic refrigerants

YZ Zheng, M Evangelisti, REP Winpenny - Chemical Science, 2011 - pubs.rsc.org
Three 3d–4f phosphonate complexes,[CoII8GdIII8 (μ3-OH) 4 (NO3) 4 (O3PtBu) 8 (O2CtBu)
16],[CoII8GdIII4 (O3PtBu) 6 (O2CtBu) 16] and [CoII4GdIII6 (O3PCH2Ph) 6 (O2CtBu) 14 …

A dodecanuclear heterometallic dysprosium–cobalt wheel exhibiting single-molecule magnet behaviour

LF Zou, L Zhao, YN Guo, GM Yu, Y Guo… - Chemical …, 2011 - pubs.rsc.org
A dodecanuclear heterometallic dysprosium–cobalt wheel exhibiting single-molecule magnet
behaviour - Chemical Communications (RSC Publishing) DOI:10.1039/C1CC12405F Royal …