Theory and practice of modeling van der Waals interactions in electronic-structure calculations

M Stöhr, T Van Voorhis, A Tkatchenko - Chemical Society Reviews, 2019 - pubs.rsc.org
The accurate description of long-range electron correlation, most prominently including van
der Waals (vdW) dispersion interactions, represents a particularly challenging task in the …

r2SCAN-3c: A “Swiss army knife” composite electronic-structure method

S Grimme, A Hansen, S Ehlert… - The Journal of Chemical …, 2021 - pubs.aip.org
The recently proposed r 2 SCAN meta-generalized-gradient approximation (mGGA) of
Furness and co-workers is used to construct an efficient composite electronic-structure …

Deep-neural-network solution of the electronic Schrödinger equation

J Hermann, Z Schätzle, F Noé - Nature Chemistry, 2020 - nature.com
The electronic Schrödinger equation can only be solved analytically for the hydrogen atom,
and the numerically exact full configuration-interaction method is exponentially expensive in …

The first-principles phase diagram of monolayer nanoconfined water

V Kapil, C Schran, A Zen, J Chen, CJ Pickard… - Nature, 2022 - nature.com
Water in nanoscale cavities is ubiquitous and of central importance to everyday phenomena
in geology and biology. However, the properties of nanoscale water can be substantially …

Crystal structure prediction methods for organic molecules: State of the art

DH Bowskill, IJ Sugden… - Annual Review of …, 2021 - annualreviews.org
The prediction of the crystal structures that a given organic molecule is likely to form is an
important theoretical problem of significant interest for the pharmaceutical and agrochemical …

B97-3c: A revised low-cost variant of the B97-D density functional method

JG Brandenburg, C Bannwarth, A Hansen… - The Journal of chemical …, 2018 - pubs.aip.org
A revised version of the well-established B97-D density functional approximation with
general applicability for chemical properties of large systems is proposed. Like B97-D, it is …

Extension and evaluation of the D4 London-dispersion model for periodic systems

E Caldeweyher, JM Mewes, S Ehlert… - Physical Chemistry …, 2020 - pubs.rsc.org
We present an extension of the DFT-D4 model [J. Chem. Phys., 2019, 150, 154122] for
periodic systems. The main new ingredients are additional reference polarizabilities for …

Many-body methods for surface chemistry come of age: Achieving consensus with experiments

BX Shi, A Zen, V Kapil, PR Nagy… - Journal of the …, 2023 - ACS Publications
The adsorption energy of a molecule onto the surface of a material underpins a wide array of
applications, spanning heterogeneous catalysis, gas storage, and many more. It is the key …

QMCPACK: an open source ab initio quantum Monte Carlo package for the electronic structure of atoms, molecules and solids

J Kim, AD Baczewski, TD Beaudet… - Journal of Physics …, 2018 - iopscience.iop.org
QMCPACK is an open source quantum Monte Carlo package for ab initio electronic
structure calculations. It supports calculations of metallic and insulating solids, molecules …

[HTML][HTML] r2SCAN-D4: Dispersion corrected meta-generalized gradient approximation for general chemical applications

S Ehlert, U Huniar, J Ning, JW Furness, J Sun… - The Journal of …, 2021 - pubs.aip.org
We combine a regularized variant of the strongly constrained and appropriately normed
semilocal density functional [J. Sun, A. Ruzsinszky, and JP Perdew, Phys. Rev. Lett. 115 …