Interface Induced by Hydrothermal Aging Boosts the Low-Temperature Activity of Cu-SSZ-13 for Selective Catalytic Reduction of NOx

L Jia, L Zhang, B Liu, H Cheng, H Li… - Environmental …, 2024 - ACS Publications
Hitherto, sulfur poisoning and hydrothermal aging have still been the challenges faced in
practical applications of the Cu-SSZ-13 catalyst for the selective catalytic reduction (SCR) of …

[HTML][HTML] Advances and perspectives from a decade of collaborative efforts on zeolites for selective catalytic reduction of NOx

PNR Vennestrøm, JR Thøgersen… - Microporous and …, 2023 - Elsevier
Nitrogen oxides (NO x) is a major air pollutant and its release is regulated by increasingly
stringent legislation. Selective catalytic reduction using ammonia as a reductant (NH 3-SCR) …

Lead-chlorine synergistic immobilization mechanism in municipal solid waste incineration fly ash (MSWIFA)-based magnesium potassium phosphate cement

X Cao, Q Zhang, W Yang, L Fang, S Liu, R Ma… - Journal of Hazardous …, 2023 - Elsevier
The high chlorine (Cl) and lead (Pb) content characteristics of municipal solid waste
incineration fly ash (MSWIFA) pose environmental risks and hinder resource utilization …

Dual‐Metal Sites Drive Tandem Electrocatalytic CO2 to C2+ Products

G **e, W Guo, Z Fang, Z Duan, X Lang… - Angewandte …, 2024 - Wiley Online Library
The electrochemical conversion of CO2 into valuable chemicals is a promising route for
renowable energy storage and the mitigation of greenhouse gas emission, and production …

Sulfur Migration Enhanced Proton-Coupled Electron Transfer for Efficient CO2 Desorption with Core-Shelled C@Mn3O4

L **ng, Z Chen, G Zhan, Z Huang, M Li… - Environmental …, 2024 - ACS Publications
Transforming hazardous species into active sites by ingenious material design was a
promising and positive strategy to improve catalytic reactions in industrial applications. To …

The [(NH3)4Cu2O2]2+‐Peroxo Complex as the Key Intermediate for NH3‐SCR Activity and Deactivation of Cu‐CHA Catalysts.

TVW Janssens, E Borfecchia, KA Lomachenko… - …, 2024 - Wiley Online Library
Abstract In NH3‐SCR over Cu‐CHA catalysts in the low‐temperature range 150–300° C, the
activation of oxygen occurs via oxidation of a pair of mobile (NH3) 2CuI‐complexes located …

Impact of sulfur exposure on high-temperature Cu speciation in SSZ-13 Zeolites

K Mandal, P Rani, YR Chen, A Wijerathne… - Applied Catalysis B …, 2024 - Elsevier
Metal active sites exchanged in zeolites dynamically change speciation under different
reaction conditions, resulting in condition-dependent reactivity with gas molecules. This is of …

Competition between Mononuclear and Binuclear Copper Sites across Different Zeolite Topologies

A Wijerathne, A Sawyer, R Daya, C Paolucci - JACS Au, 2024 - ACS Publications
A key challenge for metal-exchanged zeolites is the determination of metal cation speciation
and nuclearity under synthesis and reaction conditions. Copper-exchanged zeolites, which …

Elucidating the reaction mechanism of SO 2 with Cu-CHA catalysts for NH 3-SCR by X-ray absorption spectroscopy

AY Molokova, RK Abasabadi, E Borfecchia… - Chemical …, 2023 - pubs.rsc.org
The application of Cu-CHA catalysts for the selective catalytic reduction of NOx by ammonia
(NH3-SCR) in exhaust systems of diesel vehicles requires the use of fuel with low sulfur …

[HTML][HTML] Mechanism for SO2 poisoning of Cu-CHA during low temperature NH3-SCR

JD Bjerregaard, M Votsmeier, H Groenbeck - Journal of Catalysis, 2023 - Elsevier
Abstract Density Functional Theory (DFT) calculations are used to investigate low
temperature SO 2 deactivation of Cu-CHA during ammonia assisted selective catalytic …