Structural chemistry of uranium phosphonates

W Yang, TG Parker, ZM Sun - Coordination Chemistry Reviews, 2015 - Elsevier
Uranium phosphonates, an important class of actinide-organic coordination polymers,
exhibit an exceptionally diverse and broad range of crystal structures. A variety of structure …

Phosphate and illite colloid pose a synergistic risk of enhanced uranium transport in groundwater: A challenge for phosphate immobilization remediation of uranium …

X Wei, X Shi, M Yang, Q Tan, Z Xu, B Ma, D Pan, W Wu - Water Research, 2024 - Elsevier
The phosphorus-containing reagents have been proposed to remediate the uranium
contaminated sites due to the formation of insoluble uranyl phosphate mineralization …

Oxo Clusters of 5f Elements

S Hickam, PC Burns - Recent Development in Clusters of Rare Earths and …, 2017 - Springer
The chemistry of the 5 f elements has been studied for decades, primarily driven by nuclear
security and the nuclear-fuel cycle. A young subset of this field, the synthesis of actinide …

Uranyl-Promoted Peroxide Generation: Synthesis and Characterization of Three Uranyl Peroxo [(UO2)2(O2)] Complexes

SG Thangavelu, CL Cahill - Inorganic chemistry, 2015 - ACS Publications
Three novel uranyl (VI) peroxide complexes,[(UO2) 2 (CH3COO) 2 (O2)(C10H8N2)](1),[(
UO2) 2 (CH3COO) 2 (O2)(C12H12N2)](2), and [(UO2) 3 (CH3COO) 4 (O2)(C15H11N3) …

Construction of uranyl organic hybrids by phosphonate and in situ generated carboxyphosphonate ligands

C Liu, W Yang, N Qu, LJ Li, QJ Pan, ZM Sun - Inorganic Chemistry, 2017 - ACS Publications
The hydrothermal reaction of uranyl ions with (5-methyl-1, 3-phenylene) diphosphonic acid
(H4MPDP) in the presence of additives such as nitric acid, N-bearing species, and …

Self‐Assembly of Uranyl–Peroxide Nanocapsules in Basic Peroxidic Environments

P Miró, B Vlaisavljevich, A Gil, PC Burns… - … A European Journal, 2016 - Wiley Online Library
A wide range of uranyl–peroxide nanocapsules have been synthesized using very simple
reactants in basic media; however, little is known about the process to form these species …

Improved Energy Transfer in the Sensitization of Americium Enables Observation of Circularly Polarized Luminescence

JJ Woods, JN Wacker, A Peterson… - Angewandte …, 2024 - Wiley Online Library
The first example of circularly polarized luminescence (CPL) from a molecular americium
(Am) complex is reported. Coordination of Am (III) by a combination of …

Supramolecular assembly of geometrically unstable hybrid organic–inorganic uranyl peroxide cage clusters and their transformations

M Xu, H Traustason, FD Bo, S Hickam… - Journal of the …, 2019 - ACS Publications
An aromatic ligand was introduced into the synthesis of a uranyl peroxide polyoxometalate
formulated as K32 (UO2) 19 (O2) 26 (OH) 2 (C6H4P2O6) 4· 65H2O that consists of a unique …

Structural variations of the first family of heterometallic uranyl carboxyphosphinate assemblies by synergy between carboxyphosphinate and imidazole ligands

W Yang, D Wu, C Liu, QJ Pan, ZM Sun - Crystal Growth & Design, 2016 - ACS Publications
Hydrothermal reactions of uranyl acetate and a series of transition metal acetates with a
carboxyphosphinate and auxiliary N-donor ligands gave rise to the formation of eight …

Occurrence of polyoxouranium motifs in uranyl organic networks constructed by using silicon-centered carboxylate linkers: structures, spectroscopy and computation

C Liu, XX Yang, S Niu, XY Yi, QJ Pan - Dalton Transactions, 2020 - pubs.rsc.org
Four novel polyoxouranium-based uranyl carboxylates have been constructed by using a
combination of three silicon-centered carboxylate ligands and polyoxouranium building …