Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

The chemistry of the early to middle actinide elements (Th− Cm) is of critical importance to
the nuclear energy industry. A need for knowledge of the chemical behavior and speciation …

The synthesis and characterization of the complexes Mo [N (R) Ar] 3 (R= C (CD3) 2CH3, Ar=
3, 5-C6H3Me2),(μ-N2){Mo [N (R) Ar] 3} 2,(μ-15N2){Mo [N (R) Ar] 3} 2, NMo [N (R) Ar] 3 …

In the last few years, considerable progress has been made in the synthesis and
characterization of complexes containing actinide–ligand multiple bonds, especially in …

By 1911, the atomic weight of uranium had been refined to 238.5 (Gmelin, vol. A2, 1980a).
The natural isotope 235 U was discovered in 1935 by mass spectrometry. The artificial …

Single-molecule magnets (SMMs) are compounds that, below a blocking temperature,
exhibit stable magnetization purely of molecular origin, and not caused by long-range …

Over 70 years of chemical investigations have shown that plutonium exhibits some of the
most complicated chemistry in the periodic table. Six Pu oxidation states have been …

The significant interest in actinide bonding has recently focused on novel compounds with
exotic oxidation states. However, the difficulty in obtaining relevant high-quality experimental …

This chapter reviews the reaction chemistry of uranium complexes with small molecules of
industrial and biological importance. Specifically, carbon monoxide (CO), nitrogen monoxide …

Lead has been used as a heavy atom derivative to solve the phase problem in the crystal
structures of a variety of protein including the calcium proteins calmodulin and …