Asymmetric organocatalytic synthesis of chiral homoallylic amines

NS Kondratyev, AV Malkov - Beilstein Journal of Organic …, 2024 - beilstein-journals.org
In recent decades, the chiral allylation of imines emerged as a key methodology in the
synthesis of alkaloids and natural products with 4-, 5-and 6-membered cyclic amine motifs …

Synthesis of 7-azabicyclo [4.3. 1] decane ring systems from tricarbonyl (tropone) iron via intramolecular Heck reactions

AH Shoemaker, EA Foker, EP Uttaro… - Beilstein Journal of …, 2023 - beilstein-journals.org
Abstract The 7-azabicyclo [4.3. 1] decane ring system, common to a number of biologically
active alkaloids, was accessed from tropone (via its η 4-diene complex with Fe (CO) 3) in a …