Selective photocatalytic C–F borylation of polyfluoroarenes by Rh/Ni dual catalysis providing valuable fluorinated arylboronate esters

YM Tian, XN Guo, MW Kuntze-Fechner… - Journal of the …, 2018 - ACS Publications
A highly selective and general photocatalytic C–F borylation protocol that employs a
rhodium biphenyl complex as a triplet sensitizer and the nickel catalyst [Ni (IMes) 2](IMes= 1 …

Ultrafast photophysics of para-substituted 2, 5-bis (arylethynyl) rhodacyclopentadienes: thermally activated intersystem crossing

Z Guo, Y Wang, J Heitmüller, C Sieck, A Prüfer… - Chemical …, 2024 - pubs.rsc.org
2, 5-Bis (phenylethynyl) rhodacyclopentadienes (RCPDs), as a type of Rh (III) complex,
exhibit unusually intense fluorescence and slow intersystem crossing (ISC) due to weak …

Properties and prospects for rhenium (i) tricarbonyl N-heterocyclic carbene complexes

PV Simpson, M Falasca, M Massi - Chemical Communications, 2018 - pubs.rsc.org
Re (I) complexes bound to π-conjugated bidentate N-heterocyclic carbene ligands with
formulation Re (CO) 3 (N^ NHC) L (where N^ NHC represents an imidazole or …

Symmetric and non-symmetric anthracen-diyl bis (alkylidynes)

BJ Frogley, AF Hill, SS Welsh - Dalton Transactions, 2021 - pubs.rsc.org
Three examples of 9-bromo-10-(alkylidynyl) anthracenes,[W {CC (C6H4) 2CBr}(CO) 2
(L)](L= hydrotris (dimethylpyrazol-1-yl) borate Tp*, hydrotris (pyrazol-1-yl) borate Tp …

Highly Conjugated π‐Systems Arising from Cannibalistic Hexadehydro‐Diels–Alder Couplings: Cleavage of C− C Single and Triple Bonds

J Maier, M Deutsch, J Merz, Q Ye… - … A European Journal, 2020 - Wiley Online Library
We have investigated the cannibalistic self‐trap** reaction of an ortho‐benzyne derivative
generated from 1, 11‐bis (p‐tolyl) undeca‐1, 3, 8, 10‐tetrayne in an HDDA reaction. Without …

Synthesis and reactivity of 9, 10-bis (4-trimethylsilylethynylbuta-1, 3-diynyl) anthracene derived chromophores

BJ Frogley, AF Hill - Dalton Transactions, 2023 - pubs.rsc.org
9, 10-Bis (4-trimethylsilylethynylbutadiynyl) anthracene is readily availabe from the reaction
of anthraquinone and LiCCCCSiMe3 followed by reduction with Sn (II) and serves as a …

Synthesis of rhenacyclopentadienes and η2: η2-diyne complexes from a labile dirhenium carbonyl and π-conjugated 1, 7-octadiynes: Structural and photophysical …

C Cardozo, A Mendoza, G Farias, ALB Formiga… - Journal of …, 2019 - Elsevier
A series of dirhenium carbonyl compounds containing π-conjugated diyne ligands and
symmetrical 2, 5-bis (aryl) rhenacyclopentadienes has been synthesized by reaction of [Re 2 …

[BOOK][B] Synthesis, group 10 metal-catalyzed cyclization reactions and hydroboration of polyynes

R Ricker - 2022 - search.proquest.com
Abstract Bisdiynes undergo Pd (0)-catalyzed cyclization, forming azulene and naphthalene
products. When dibenzylideneacetone is present in the reaction, it undergoes a [2+ 2+ 2] …

Selective CX and CH Borylation by N-Heterocyclic Carbene Nickel (0) Complex

Y Tian - 2021 - opus.bibliothek.uni-wuerzburg.de
Organoboron compounds are important building blocks in organic synthesis, materials
science, and drug discovery. The development of practical and convenient ways to …

[PDF][PDF] Reactions of rhodium (I) with diynes and studies of the photophysical behavior of the luminescent products

FT Kerner - 2021 - d-nb.info
Cyclic compounds comprise a series of atoms connected to form a ring, the size of which
can vary from three to several 100 atoms. These ring systems can consist of only carbon …