Water adsorption in MOFs: structures and applications

B Zhang, Z Zhu, X Wang, X Liu… - Advanced Functional …, 2024 - Wiley Online Library
Metal–organic frameworks (MOFs) are superior sorbents for water adsorption‐based
applications. The unique step‐like water isotherm at a MOF‐specific relative pressure allows …

Metal-organic frameworks for water vapor adsorption

L Shi, KO Kirlikovali, Z Chen, OK Farha - Chem, 2024 - cell.com
The development of stable physisorbents for water adsorption-related applications has
attracted considerable attention owing to the demands of efficient water vapor capture in …

ChatGPT chemistry assistant for text mining and the prediction of MOF synthesis

Z Zheng, O Zhang, C Borgs, JT Chayes… - Journal of the …, 2023 - ACS Publications
We use prompt engineering to guide ChatGPT in the automation of text mining of metal–
organic framework (MOF) synthesis conditions from diverse formats and styles of the …

Endowing porphyrinic metal–organic frameworks with high stability by a linker desymmetrization strategy

W Han, X Ma, J Wang, F Leng, C **e… - Journal of the American …, 2023 - ACS Publications
The fabricating of metal–organic frameworks (MOFs) that integrate high stability and
functionality remains a long-term pursuit yet a great challenge. Herein, we develop a linker …

Reticular Design of Precise Linker Installation into a Zirconium Metal–Organic Framework to Reinforce Hydrolytic Stability

Y Chen, KB Idrees, MR Mian, FA Son… - Journal of the …, 2023 - ACS Publications
Reticular chemistry allows for the rational assembly of metal–organic frameworks (MOFs)
with designed structures and desirable functionalities for advanced applications. However, it …

Rational design of stable functional metal–organic frameworks

Z Chen, KO Kirlikovali, L Shi, OK Farha - Materials horizons, 2023 - pubs.rsc.org
Functional porous metal–organic frameworks (MOFs) have been explored for a number of
potential applications in catalysis, chemical sensing, water capture, gas storage, and …

Metal–organic frameworks and their composites for environmental applications

Q Zhang, H Yang, T Zhou, X Chen, W Li… - Advanced …, 2022 - Wiley Online Library
From the point of view of the ecological environment, contaminants such as heavy metal
ions or toxic gases have caused harmful impacts on the environment and human health, and …

The growth mechanism of a conductive MOF thin film in spray‐based layer‐by‐layer liquid phase epitaxy

R Zheng, ZH Fu, WH Deng, Y Wen… - Angewandte Chemie …, 2022 - Wiley Online Library
The layer‐by‐layer liquid‐phase epitaxy (LBL‐LPE) method is widely used in preparing
metal–organic framework (MOF) thin films with the merits of controlling thickness and out‐of …

Leveraging Isoreticular Principle to Elucidate the Key Role of Inherent Hydrogen-Bonding Anchoring Sites in Enhancing Water Sorption Cyclability of Zr (IV) Metal …

W Gong, Y Geng, P Gao, J Zhang, K Zhou… - Journal of the …, 2024 - ACS Publications
Water adsorption/desorption cyclability of porous materials is a prerequisite for diverse
applications, including atmospheric water harvesting (AWH), humidity autocontrol (HAC) …

Optimized sieving effect for ethanol/water separation by ultramicroporous MOFs

X Zheng, L Chen, H Zhang, Z Yao… - Angewandte Chemie …, 2023 - Wiley Online Library
High‐purity ethanol is a promising renewable energy resource, however separating ethanol
from trace amount of water is extremely challenging. Herein, two ultramicroporous MOFs …