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Designing catalysts for olefin polymerization and copolymerization: beyond electronic and steric tuning
More than 50 years have passed since Ziegler and Natta shared the Nobel Prize in
Chemistry for their discovery of olefin polymerization catalysts. The field of metal-catalysed …
Chemistry for their discovery of olefin polymerization catalysts. The field of metal-catalysed …
Emerging palladium and nickel catalysts for copolymerization of olefins with polar monomers
Transition‐metal‐catalyzed copolymerization of olefins with polar monomers represents a
challenge because of the large variety of substrate‐induced side reactions. However, this …
challenge because of the large variety of substrate‐induced side reactions. However, this …
[HTML][HTML] Recent advances on α-diimine Ni and Pd complexes for catalyzed ethylene (Co) polymerization: A comprehensive review
Abstract α-Diimine Ni and Pd complexes are one of the most examined late-transition
organometallics in the application of catalyzed ethylene (co) polymerization. These …
organometallics in the application of catalyzed ethylene (co) polymerization. These …
Stereochemical enhancement of polymer properties
The importance of stereochemistry to the function of molecules is generally well understood.
However, to date, control over stereochemistry and its potential to influence properties of the …
However, to date, control over stereochemistry and its potential to influence properties of the …
Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization of γ-butyrolactone
Ring-opening polymerization (ROP) is a powerful synthetic methodology for the chemical
synthesis of technologically important biodegradable aliphatic polyesters from cyclic esters …
synthesis of technologically important biodegradable aliphatic polyesters from cyclic esters …
Atom transfer radical polymerization: billion times more active catalysts and new initiation systems
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …
established as a powerful technique to prepare precisely defined polymeric materials. This …
Polymerization of polar monomers mediated by main-group Lewis acid–base pairs
The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …
polymerization reactions or processes continues to be crucial for the synthesis of important …
Palladium and nickel catalyzed chain walking olefin polymerization and copolymerization
In this perspective, recent developments on palladium and nickel mediated chain walking
olefin polymerization and copolymerization with polar functionalized comonomers are …
olefin polymerization and copolymerization with polar functionalized comonomers are …
Recent advances in Ni-mediated ethylene chain growth: Nimine-donor ligand effects on catalytic activity, thermal stability and oligo-/polymer structure
Homogeneous nickel catalysts have a considerable track record for mediating ethylene
chain growth in the form of oligomerization and more recently polymerization. Within the …
chain growth in the form of oligomerization and more recently polymerization. Within the …
Half-sandwich rare-earth-catalyzed olefin polymerization, carbometalation, and hydroarylation
M Nishiura, F Guo, Z Hou - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus The search for new catalysts for more efficient, selective chemical
transformations and for the synthesis of new functional materials has been a long-standing …
transformations and for the synthesis of new functional materials has been a long-standing …