Boron clusters in luminescent materials

S Mukherjee, P Thilagar - Chemical Communications, 2016 - pubs.rsc.org
In recent times, luminescent materials with tunable emission properties have found
applications in almost all aspects of modern material sciences. Any discussion on the recent …

Recent developments of photoactive Cu (I) and Ag (I) complexes with diphosphine and related ligands

H Takeda, A Kobayashi, K Tsuge - Coordination Chemistry Reviews, 2022 - Elsevier
In the past two decades, emissive Cu (I) complexes have been synthesized with various
ligands, revealing their interesting and useful photophysical properties such as high …

“Quick-Silver” from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes

R Hamze, S Shi, SC Kapper… - Journal of the …, 2019 - ACS Publications
A systematic study is presented on the physical and photophysical properties of
isoelectronic and isostructural Cu, Ag, and Au complexes with a common amide (N …

Photoinitiated Oxidative Addition of CF3I to Gold(I) and Facile Aryl-CF3 Reductive Elimination

MS Winston, WJ Wolf, FD Toste - Journal of the American …, 2014 - ACS Publications
Herein we report the mechanism of oxidative addition of CF3I to Au (I), and remarkably fast
Caryl–CF3 bond reductive elimination from Au (III) cations. CF3I undergoes a fast, formal …

Transition metal complexes with carboranylphosphine ligands

IB Sivaev, MY Stogniy, VI Bregadze - Coordination Chemistry Reviews, 2021 - Elsevier
Synthesis and structure of transition metal complexes with phosphine ligands derived from
icosahedral dicarbaboranes C 2 B 10 H 12, monocarbaboranes [CB 9 H 10]− and [CB 11 H …

Closo- or Nido-Carborane Diphosphane as Responsible for Strong Thermochromism or Time Activated Delayed Fluorescence (TADF) in [Cu(N^N)(P^P)]0/+

A Alconchel, O Crespo, P García-Orduña… - Inorganic …, 2021 - ACS Publications
Ortho-closo or ortho-nido-carborane-diphosphanes have been selected to prepare the
heteroleptic cationic or neutral [Cu (N^ N){(PPh2) 2C2B10H10}] PF6 (1) and [Cu (N …

Metal promoted charge and hapticities of phosphines: The uniqueness of carboranylphosphines

AR Popescu, F Teixidor, C Vinas - Coordination Chemistry Reviews, 2014 - Elsevier
The accurate selection of a ligand for a metal-catalyzed homogeneous reaction can be as
decisive as the selection of the metal. Incorporating a carborane cage as a backbone to …

Transition‐Metal‐Catalyzed Regioselective Functionalization of Monophosphino‐o‐Carboranes

ZY Zhang, X Zhang, J Yuan, CD Yue… - … A European Journal, 2020 - Wiley Online Library
A facile approach to the synthesis of diaryl‐and dialkyl‐substituted monophosphino‐o‐
carboranes by rhodium (I)‐catalyzed phosphine‐directed B3, 6− H activation has been …

Photoluminescence properties of TADF-emitting three-coordinate silver (I) halide complexes with diphosphine ligands: a comparison study with copper (I) complexes

M Osawa, M Hashimoto, I Kawata, M Hoshino - Dalton Transactions, 2017 - pubs.rsc.org
Synthesis and X-ray structures of silver (I) bromide complexes with diphosphine ligands
LMe, LEt, and LiPr are described, where LMe= 1, 2-bis [bis (2-methylphenyl) phosphino] …

Synthesis and Photophysical Properties of T‐Shaped Coinage‐Metal Complexes

G Kleinhans, AKW Chan, MY Leung… - … A European Journal, 2020 - Wiley Online Library
The photophysical properties of a series of T‐shaped coinage d10 metal complexes,
supported by a bis (mesoionic carbene) carbazolide (CNC) pincer ligand, are explored. The …