Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

C Papatriantafyllopoulou, EE Moushi… - Chemical Society …, 2016 - pubs.rsc.org
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

Synthesis of 3d Metallic Single-Molecule Magnets

G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

Quantum tunneling of magnetization in lanthanide single-molecule magnets, bis (phthalocyaninato) terbium and bis (phthalocyaninato)-dysprosium anions

N Ishikawa, M Sugita, W Wernsdorfer - arxiv preprint cond-mat/0506583, 2005 - arxiv.org
Magnetization versus field measurements were performed on single crystals of [(Pc) 2TbIII0.
02YIII0. 98]^ TBA+ and [(Pc) 2DyIII0. 02YIII0. 98]^ TBA+ (Pc: phthalocyaninato, TBA …

Nuclear spin driven quantum tunneling of magnetization in a new lanthanide single-molecule magnet: bis (phthalocyaninato) holmium anion

N Ishikawa, M Sugita… - Journal of the American …, 2005 - ACS Publications
The first measurements of magnetization hysteresis loops on a diluted single crystal of [(Pc)
2Ho]-⊙ TBA+ (Pc= phthalocyaninato, TBA= tetrabutylammonium) in the subkelvin …

Initial observation of magnetization hysteresis and quantum tunneling in mixed manganese− lanthanide single-molecule magnets

A Mishra, W Wernsdorfer, KA Abboud… - Journal of the …, 2004 - ACS Publications
The preparation of a new family of mixed transition metal/lanthanide clusters is reported. The
reaction of [Mn3O (O2CPh) 6 (py) 2 (H2O)] with Ln (NO3) 3 (Ln= Nd, Gd, Dy, Ho, and Eu) in …

Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII−FeIII−MnIII Trinuclear Single-Molecule Magnet with an ST = 9/2 Spin Ground …

M Ferbinteanu, H Miyasaka… - Journal of the …, 2005 - ACS Publications
The cyano-bridged trinuclear compound,(NEt4)[Mn2 (salmen) 2 (MeOH) 2Fe (CN)
6](1)(salmen2-= rac-N, N '-(1-methylethylene) bis (salicylideneiminate)), reported previously …

Hierarchical Assembly of a {MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism

YK Deng, HF Su, JH Xu, WG Wang… - Journal of the …, 2016 - ACS Publications
In search of functional molecular materials and the study of their formation mechanism, we
report the elucidation of a hierarchical step-by-step formation from monomer (Mn) to …