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Advances in atomistic modeling and understanding of drying shrinkage in cementitious materials
Despite more than a century of research, drying shrinkage still causes unwanted stresses
and cracks in our concrete infrastructures. This is partly due to the lack of understanding of …
and cracks in our concrete infrastructures. This is partly due to the lack of understanding of …
Advances in characterizing and understanding the microstructure of cementitious materials
Progress in microstructural characterization methods is summarized. Special attention is
given to advanced probes, such as X-ray imaging and spectroscopy, 1 H NMR relaxometry …
given to advanced probes, such as X-ray imaging and spectroscopy, 1 H NMR relaxometry …
Structure and morphology of calcium-silicate-hydrates cross-linked with dipodal organosilanes
Coupling of organic and inorganic chemistry presents a new degree of freedom in nano-
engineering of thermo-mechanical properties of cement-based materials. Despite these vast …
engineering of thermo-mechanical properties of cement-based materials. Despite these vast …
Plastic deformation mechanism of calcium-silicate hydrates determined by deviatoric-stress Raman spectroscopy
Creep of the cement matrix affects the structural stability of concrete. In Portland cements,
the creep is largely controlled by the binding phase calcium-(aluminum-) silicate-hydrate, or …
the creep is largely controlled by the binding phase calcium-(aluminum-) silicate-hydrate, or …
The missing link in the bottom-up theory of mechanical properties of calcium silicate hydrate
Calcium silicate hydrate (CSH) is the primary binding phase in modern concrete. While
significant progress has been made in understanding the structure and behavior of CSH at …
significant progress has been made in understanding the structure and behavior of CSH at …
Uniaxial stress increases layer stacking disorder in calcium silicate hydrates with low calcium content
The long-term stress response of concrete is controlled by the intergrain and intragrain
interactions of calcium-silicate-hydrates (CSH), nanocrystalline forms of tobermorites. To …
interactions of calcium-silicate-hydrates (CSH), nanocrystalline forms of tobermorites. To …