Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Selectivity in Electrochemical CO2 Reduction

P Saha, S Amanullah, A Dey - Accounts of chemical research, 2022 - ACS Publications
Conspectus The electrocatalytic CO2 reduction reaction (CO2RR) to generate fixed forms of
carbons that have commercial value is a lucrative avenue to ameliorate the growing …

Bioinspired and bioderived aqueous electrocatalysis

J Barrio, A Pedersen, S Favero, H Luo, M Wang… - Chemical …, 2022 - ACS Publications
The development of efficient and sustainable electrochemical systems able to provide clean-
energy fuels and chemicals is one of the main current challenges of materials science and …

Atomically Structural Regulations of Carbon‐Based Single‐Atom Catalysts for Electrochemical CO2 Reduction

SG Han, DD Ma, QL Zhu - Small Methods, 2021 - Wiley Online Library
The electrochemical carbon dioxide reduction reaction (CO2RR) converting CO2 into value‐
added chemicals and fuels to realize carbon recycling is a solution to the problem of …

Molecular electrochemical reduction of CO2 beyond two electrons

E Boutin, M Robert - Trends in Chemistry, 2021 - cell.com
CO 2 molecular electrochemical reduction has recently led to remarkable advancements.
High performing catalysts have been prepared that mainly produce carbon monoxide (CO) …

Second Coordination Sphere Effect Shifts CO2 to CO Reduction by Iron Porphyrin from Fe0 to FeI

S Amanullah, P Gotico, M Sircoglou… - Angewandte Chemie …, 2024 - Wiley Online Library
Iron porphyrins are among the most studied molecular catalysts for carbon dioxide (CO2)
reduction and their reactivity is constantly being enhanced through the implementation of …

Bio‐Inspired Bimetallic Cooperativity Through a Hydrogen Bonding Spacer in CO2 Reduction

C Zhang, P Gotico, R Guillot, D Dragoe… - Angewandte Chemie …, 2023 - Wiley Online Library
At the core of carbon monoxide dehydrogenase (CODH) active site two metal ions together
with hydrogen bonding scheme from amino acids orchestrate the interconversion between …

Electrocatalytic CO2 Reduction: from Discrete Molecular Catalysts to Their Integrated Catalytic Materials

K Lei, B Yu **a - Chemistry–A European Journal, 2022 - Wiley Online Library
Molecular catalysts (metal complexes), with molecularly defined uniform active sites and
atomically precise structural tailorability allowing for regulating catalytic performance …

Molecular Nickel Thiolate Complexes for Electrochemical Reduction of CO2 to C1–3 Hydrocarbons

J Du, B Cheng, H Yuan, Y Tao, Y Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
We report the unprecedented electrocatalytic activity of a series of molecular nickel thiolate
complexes (1–5) in reducing CO2 to C1–3 hydrocarbons on carbon paper in pH‐neutral …

Rational Design of Earth‐Abundant Catalysts toward Sustainability

J Guo, Y Haghshenas, Y Jiao, P Kumar… - Advanced …, 2024 - Wiley Online Library
Catalysis is crucial for clean energy, green chemistry, and environmental remediation, but
traditional methods rely on expensive and scarce precious metals. This review addresses …