Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …

Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐or
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …

Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …

Well‐defined manganese complexes based on inexpensive, readily available ligands, 2,
2′: 6′, 2′′‐terpyridine and its derivatives have been prepared and employed for the …

This review discusses recent advances in the chemistry of saturated boronic acids,
boronates, and trifluoroborates. Applications of the title compounds in the design of boron …

A chemoselective hydroboration protocol with terminal alkene substrates is reported using
an electron-rich, low-valent cobalt pincer compound. The process is catalytic and leads to …

Reported is a highly enantioselective copper‐catalyzed Markovnikov protoboration of
unactivated terminal alkenes. A variety of simple and abundant feedstock α‐olefins bearing …

1, 3-Functionalized cyclobutane structural motifs are ubiquitous in natural products and
pharmaceuticals. Photoinduced alkylation of bicyclo [1.1. 0] butanes (BCBs) offers a step …

We report the first enantioselective Rh-catalyzed Markovnikov hydroboration of unactivated
terminal alkenes. Using a novel sp2–sp3 hybridized diboron reagent and water as a proton …

A MnI‐catalyzed hydroboration of terminal alkenes and a 1, 2‐diboration of terminal alkynes
with pinacolborane (HBPin) is described. For alkenes, anti‐Markovnikov hydroboration …