Dehydrogenation of alkanes and aliphatic groups by pincer-ligated metal complexes
The alkyl group is the most common component of organic molecules and the most difficult
to selectively functionalize. The development of catalysts for dehydrogenation of alkyl …
to selectively functionalize. The development of catalysts for dehydrogenation of alkyl …
Pincer‐type complexes for catalytic (De) hydrogenation and transfer (De) hydrogenation reactions: recent progress
S Werkmeister, J Neumann, K Junge… - … –A European Journal, 2015 - Wiley Online Library
Pincer complexes are becoming increasingly important for organometallic chemistry and
organic synthesis. Since numerous applications for such catalysts have been developed in …
organic synthesis. Since numerous applications for such catalysts have been developed in …
Dehydrogenation and related reactions catalyzed by iridium pincer complexes
Since the seminal reports by Shaw and co-workers in the mid-1970s, 1-7 the chemistry of
pincer-ligated transition-metal complexes has experienced tremendous development and …
pincer-ligated transition-metal complexes has experienced tremendous development and …
Transfer hydrogenation of alkenes using ethanol catalyzed by a NCP pincer iridium complex: scope and mechanism
Y Wang, Z Huang, X Leng, H Zhu, G Liu… - Journal of the …, 2018 - ACS Publications
The first general catalytic approach to effecting transfer hydrogenation (TH) of unactivated
alkenes using ethanol as the hydrogen source is described. A new NCP-type pincer iridium …
alkenes using ethanol as the hydrogen source is described. A new NCP-type pincer iridium …
A new paradigm in pincer iridium chemistry: PCN complexes for (de) hydrogenation catalysis and beyond
Y Wang, Z Huang, G Liu, Z Huang - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The discovery and development of organometallic catalysts is of paramount
importance in modern organic synthesis, among which the ligand scaffolds play a crucial …
importance in modern organic synthesis, among which the ligand scaffolds play a crucial …
Alkane metathesis by tandem alkane-dehydrogenation–olefin-metathesis catalysis and related chemistry
Methods for the conversion of both renewable and non-petroleum fossil carbon sources to
transportation fuels that are both efficient and economically viable could greatly enhance …
transportation fuels that are both efficient and economically viable could greatly enhance …
A Covalent Triazine Framework, Functionalized with Ir/N-Heterocyclic Carbene Sites, for the Efficient Hydrogenation of CO2 to Formate
Functionalizing the recently developed porous materials such as porous organic frameworks
and coordination polymer networks with active homogeneous catalytic sites would offer new …
and coordination polymer networks with active homogeneous catalytic sites would offer new …
Selective catalytic transfer dehydrogenation of alkanes and heterocycles by an iridium pincer complex
W Yao, Y Zhang, X Jia, Z Huang - Angewandte Chemie, 2014 - Wiley Online Library
Catalytic alkane dehydrogenation is a reaction with tremendous potential for application. We
describe a highly active PSCOP‐pincer iridium catalyst for transfer dehydrogenation of cyclic …
describe a highly active PSCOP‐pincer iridium catalyst for transfer dehydrogenation of cyclic …
Polyhydrides of platinum group metals: Nonclassical interactions and σ-bond activation reactions
MA Esteruelas, AM Lopez, M Olivan - Chemical Reviews, 2016 - ACS Publications
The preparation, structure, dynamic behavior in solution, and reactivity of polyhydride
complexes of platinum group metals, described during the last three decades, are …
complexes of platinum group metals, described during the last three decades, are …
An Agostic Iridium Pincer Complex as a Highly Efficient and Selective Catalyst for Monoisomerization of 1‐Alkenes to trans‐2‐Alkenes
A unique Ir complex (tBuNCCP) Ir with the pyridine–phosphine pincer as the sole ligand,
featuring a dual agostic interaction between the Ir and two σ C− H bonds from a tBu …
featuring a dual agostic interaction between the Ir and two σ C− H bonds from a tBu …