Dehydrogenation of alkanes and aliphatic groups by pincer-ligated metal complexes

A Kumar, TM Bhatti, AS Goldman - Chemical reviews, 2017 - ACS Publications
The alkyl group is the most common component of organic molecules and the most difficult
to selectively functionalize. The development of catalysts for dehydrogenation of alkyl …

Pincer‐type complexes for catalytic (De) hydrogenation and transfer (De) hydrogenation reactions: recent progress

S Werkmeister, J Neumann, K Junge… - … –A European Journal, 2015 - Wiley Online Library
Pincer complexes are becoming increasingly important for organometallic chemistry and
organic synthesis. Since numerous applications for such catalysts have been developed in …

Dehydrogenation and related reactions catalyzed by iridium pincer complexes

J Choi, AHR MacArthur, M Brookhart… - Chemical …, 2011 - ACS Publications
Since the seminal reports by Shaw and co-workers in the mid-1970s, 1-7 the chemistry of
pincer-ligated transition-metal complexes has experienced tremendous development and …

Transfer hydrogenation of alkenes using ethanol catalyzed by a NCP pincer iridium complex: scope and mechanism

Y Wang, Z Huang, X Leng, H Zhu, G Liu… - Journal of the …, 2018 - ACS Publications
The first general catalytic approach to effecting transfer hydrogenation (TH) of unactivated
alkenes using ethanol as the hydrogen source is described. A new NCP-type pincer iridium …

A new paradigm in pincer iridium chemistry: PCN complexes for (de) hydrogenation catalysis and beyond

Y Wang, Z Huang, G Liu, Z Huang - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The discovery and development of organometallic catalysts is of paramount
importance in modern organic synthesis, among which the ligand scaffolds play a crucial …

Alkane metathesis by tandem alkane-dehydrogenation–olefin-metathesis catalysis and related chemistry

MC Haibach, S Kundu, M Brookhart… - Accounts of chemical …, 2012 - ACS Publications
Methods for the conversion of both renewable and non-petroleum fossil carbon sources to
transportation fuels that are both efficient and economically viable could greatly enhance …

A Covalent Triazine Framework, Functionalized with Ir/N-Heterocyclic Carbene Sites, for the Efficient Hydrogenation of CO2 to Formate

GH Gunasekar, K Park, V Ganesan, K Lee… - Chemistry of …, 2017 - ACS Publications
Functionalizing the recently developed porous materials such as porous organic frameworks
and coordination polymer networks with active homogeneous catalytic sites would offer new …

Selective catalytic transfer dehydrogenation of alkanes and heterocycles by an iridium pincer complex

W Yao, Y Zhang, X Jia, Z Huang - Angewandte Chemie, 2014 - Wiley Online Library
Catalytic alkane dehydrogenation is a reaction with tremendous potential for application. We
describe a highly active PSCOP‐pincer iridium catalyst for transfer dehydrogenation of cyclic …

Polyhydrides of platinum group metals: Nonclassical interactions and σ-bond activation reactions

MA Esteruelas, AM Lopez, M Olivan - Chemical Reviews, 2016 - ACS Publications
The preparation, structure, dynamic behavior in solution, and reactivity of polyhydride
complexes of platinum group metals, described during the last three decades, are …

An Agostic Iridium Pincer Complex as a Highly Efficient and Selective Catalyst for Monoisomerization of 1‐Alkenes to trans‐2‐Alkenes

Y Wang, C Qin, X Jia, X Leng… - Angewandte Chemie …, 2017 - Wiley Online Library
A unique Ir complex (tBuNCCP) Ir with the pyridine–phosphine pincer as the sole ligand,
featuring a dual agostic interaction between the Ir and two σ C− H bonds from a tBu …