Recent advances in triplet–triplet annihilation upconversion and singlet fission, towards solar energy applications
Solar energy is an ample renewable energy resource, with photovoltaic (PV) technology
enabling a direct route from light to electricity. Currently, PVs are limited in photon …
enabling a direct route from light to electricity. Currently, PVs are limited in photon …
Molecular insights and concepts to engineer singlet fission energy conversion devices
In this Review, we showcase the fundamental processes of intermolecular and
intramolecular singlet fission (SF). Furthermore we prioritize the information, which is …
intramolecular singlet fission (SF). Furthermore we prioritize the information, which is …
What next for singlet fission in photovoltaics? The fate of triplet and triplet-pair excitons
Exciton multiplication through singlet fission (SF) has the potential to surpass the detailed-
balance efficiency limit of single-junction photovoltaic (PV) devices. However, energy loss …
balance efficiency limit of single-junction photovoltaic (PV) devices. However, energy loss …
Role of Singlet and Triplet Excited States in the Oxygen-Mediated Photophysics and Photodegradation of Polyacenes
Polyacenes, such as tetracene and pentacene, are common model systems for the study of
photophysical phenomena such as singlet fission (SF) and triplet fusion, processes which …
photophysical phenomena such as singlet fission (SF) and triplet fusion, processes which …
Supramolecular singlet fission of pentacene dimers within polyaromatic capsules
We herein report a new set of supramolecular nanotools for the generation and modulation
of singlet fission (SF) of noncovalent/covalent pentacene dimers. Two molecules of a …
of singlet fission (SF) of noncovalent/covalent pentacene dimers. Two molecules of a …
Altering singlet fission pathways in perylene-dimers; perylene-diimide versus perylene-monoimide
We used a systematic approach to shed light on the inherent differences in perylenes,
namely monoimides versus diimides, including coplanarity and dipole moment, and their …
namely monoimides versus diimides, including coplanarity and dipole moment, and their …
Intramolecular Triplet Diffusion Facilitates Triplet Dissociation in a Pentacene Hexamer
Triplet dynamics in singlet fission depend strongly on the strength of the electronic coupling.
Covalent systems in solution offer precise control over such couplings. Nonetheless, efficient …
Covalent systems in solution offer precise control over such couplings. Nonetheless, efficient …
Parallel versus twisted pentacenes: Conformational impact on singlet fission
We placed two pentacene chromophores at the termini of a diacetylene linker to investigate
the impact of excitation wavelength, conformational flexibility, and vibronic coupling on …
the impact of excitation wavelength, conformational flexibility, and vibronic coupling on …
[HTML][HTML] Vibrational probe of the origin of singlet exciton fission in TIPS-pentacene solutions
We use native vibrational modes of the model singlet fission chromophore 6, 13-bis
(triisopropylsilylethynyl) pentacene (TIPS-Pn) to examine the origins of singlet fission in …
(triisopropylsilylethynyl) pentacene (TIPS-Pn) to examine the origins of singlet fission in …
Higher-energy triplet-pair states in polyenes and their role in intramolecular singlet fission
Probing extended polyene systems with energy in excess of the bright state (1 1 B u+/S 2)
band edge generates triplets via singlet fission. This process is not thought to involve the 2 1 …
band edge generates triplets via singlet fission. This process is not thought to involve the 2 1 …