The Heck reaction as a sharpening stone of palladium catalysis

IP Beletskaya, AV Cheprakov - Chemical Reviews, 2000 - ACS Publications
Palladium catalysis has achieved the status of an indispensable tool for both common and
state-of-theart organic synthesis. Among basic types of palladium-catalyzed transformations …

Selected patented cross-coupling reaction technologies

JP Corbet, G Mignani - Chemical reviews, 2006 - ACS Publications
Many significant products (drugs, materials, optical devices, etc.) commercialized or in the
development phase, possess aromatic carbon-carbon and aromatic carbonnitrogen bonds …

Biaryl monophosphine ligands in palladium-catalyzed C–N coupling: An updated User's guide

BT Ingoglia, CC Wagen, SL Buchwald - Tetrahedron, 2019 - Elsevier
Over the past three decades, Pd-catalyzed cross-coupling reactions have become a
mainstay of organic synthesis. In particular, catalysts derived from biaryl monophosphines …

Palladium-catalyzed cross-coupling reactions of organoboron compounds

N Miyaura, A Suzuki - Chemical reviews, 1995 - ACS Publications
Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds Page 1 Chem.
Rev. 1995, 95, 2457-2483 2457 Palladium-Catalyzed Cross-Coupling Reactions of …

Synthesis and functionalization of indoles through palladium-catalyzed reactions

S Cacchi, G Fabrizi - Chemical reviews, 2005 - ACS Publications
The substituted indole nucleus [indole is the acronym from indigo (the natural dye) and
oleum (used for the isolation)] is a structural component of a vast number of biologically …

Anionic Pd (0) and Pd (II) intermediates in palladium-catalyzed Heck and cross-coupling reactions

C Amatore, A Jutand - Accounts of Chemical Research, 2000 - ACS Publications
The anions of PdCl2L2 and Pd (OAc) 2, precursors of palladium (0) used in cross-coupling
and Heck reactions, play a crucial role in these reactions. Tricoordinated anionic complexes …

The mechanisms of the Stille reaction

P Espinet, AM Echavarren - Angewandte Chemie International …, 2004 - Wiley Online Library
Eighteen years ago in Angewandte Chemie John K. Stille reviewed a novel methodology,
which eventually became known by his name, for the coupling of organostannanes with …

Kinetic Data for the Transmetalation/Reductive Elimination in Palladium‐Catalyzed Suzuki–Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as …

C Amatore, A Jutand, G Le Duc - Chemistry–A European …, 2011 - Wiley Online Library
The mechanism of the reaction of trans‐[ArPdX (PPh3) 2](Ar= p‐Z‐C6H4; Z= CN, F, H; X= I,
Br, Cl) with Ar′ B (OH) 2 (Ar′= p‐Z′‐C6H4; Z′= CN, H, OMe) has been established in …

<? ACS-CT-START-Insert?> Update 1 of:<? ACS-CT-END-Insert?> Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions

S Cacchi, G Fabrizi - Chemical Reviews, 2011 - ACS Publications
The substituted indole nucleus [indole is the acronym fromindigo (the natural dye) and
oleum (used for the isolation)] is a structural component of a vast number of biologically …

Contribution of electrochemistry to organometallic catalysis

A Jutand - Chemical reviews, 2008 - ACS Publications
Many reactions are nowadays catalyzed by a transition metal, which not only accelerates the
reactions but allows, via its ligand (s), a fine control of the chemo-, regio-, and …