Borate ligand derived from CS2 unveiling ruthenium dithioformate and trithia-borinane complexes

A Ahmad, S Gayen, S Mishra, Z Afsan, L Vendier… - Polyhedron, 2024 - Elsevier
The reactivity of κ 2-N, S-chelated ruthenium borate complexes,[Ph 3 P (κ 2-N, SL) Ru {κ 3-
H, S, S′-H 2 B (L) 2}],(L= C 5 H 4 NS, C 7 H 4 NS 2) 1 and 3 with borate ligand derived from …

Reactivity of [(Cp*CoPh)(Cp*Co)(μ-TePh)(μ-k2-Te,H-TeBH3)] Toward [M(CO)5·THF] (M = Mo and W), CS2, and [Fe2(CO)9]

AN Pradhan, S Bairagi, S Ghosh - Inorganic Chemistry, 2024 - ACS Publications
Syntheses and structural elucidation of homo-and heterochalcogen-bridged complexes of
cobalt are described. The photolytic reaction of bimetallic hydridoborate species [(Cp …

Structural and electronic analysis of bimetallic thiolate complexes of group-5 transition metal ions

U Kaur, K Saha, S Bairagi, A Das, T Roisnel… - Journal of …, 2021 - Elsevier
The chemistry of group-5 transition metals, namely vanadium, niobium, and tantalum
supported by thiolate ligand framework, has been described. Special emphasis has been …

Role of Metals and Thiolate Ligands in the Structures and Electronic Properties of Group 5 Bimetallic–Thiolate Complexes

K Saha, U Kaur, B Raghavendra, S Ghosh - Inorganic Chemistry, 2020 - ACS Publications
Syntheses, structures, and electronic properties of group 5 metal–thiolate complexes that
exhibit unusual coordination modes of thiolate ligands have been established. Room …

Insertion of CS 2 into the Mg–H bond: synthesis and structural characterization of the magnesium dithioformate complex,[Tism PriBenz] Mg (κ 2-S 2 CH)

M Rauch, G Parkin - Dalton Transactions, 2018 - pubs.rsc.org
The tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] methyl magnesium hydride
compound,[TismPriBenz] MgH, undergoes insertion of CS2 into the Mg–H bond at room …

SAMAROCENECHALCOGENIDES (Q= S, SE, TE) AS SYNTHETIC EQUIVALENTS OF THE Q 2–SYNTHON IN REACTIONS WITH CS2

BY Savkov, TS Sukhikh, SN Konchenko - Journal of Structural Chemistry, 2022 - Springer
Reactions of decamethylsamarocene monochalcogenides (Cp*= η5-C5 (CH3) 5; Q= S (1),
Se (2), Te (3)) with carbon disulfide are studied. It is established that these reactions lead to …

New multinuclear Scaffold molybdocene-gold lidocaine complex: DNA/HSA binding, molecular docking, cytotoxicity and mechanistic insights

F Abyar, L Tabrizi - Journal of Biomolecular Structure and …, 2019 - Taylor & Francis
The new heteronuclear molybdocene-gold complex 1,[(η 5-Cp) 2 Mo II [(μ 2-η 2-dtc) 2 Nap]
Au III (LC)](PF 6),(η 5-Cp: η 5-cyclopentadienyl,(dtc) 2 Nap: 2, 7-bis (dithiocarbamate) …

Synthesis of Trithia-Borinane Complexes Stabilized in Diruthenium Core: [(Cp*Ru)21-S)(η1-CS){(CH2)2S3BR}] (R = H or SMe)

K Saha, U Kaur, R Borthakur, S Ghosh - Inorganics, 2019 - mdpi.com
The thermolysis of arachno-1 [(Cp* Ru) 2 (B3H8)(CS2H)] in the presence of tellurium
powder yielded a series of ruthenium trithia-borinane complexes:[(Cp* Ru) 2 (η1-S)(η1 …

САМАРОЦЕНХАЛЬКОГЕНИДЫ [{CP* 2 SM (THF)} 2 (μ-Q)](Q= S, SE, TE)-СИНТЕТИЧЕСКИЕ ЭКВИВАЛЕНТЫ СИНТОНА Q 2-В РЕАКЦИЯХ С CS 2

БЮ САВКОВ, ТС СУХИХ, СН КОНЧЕНКО - ЖУРНАЛ СТРУКТУРНОЙ …, 2022 - elibrary.ru
Изучены реакции монохалькогенидов декаметилсамароцена [{Cp* 2 Sm (THF)} 2 (μ-
Q)](Cp*= η 5-C 5 (CH 3) 5; Q= S (1), Se (2), Te (3)) с сероуглеродом. Установлено, что эти …